Experimentally Determined Redox Potentials of Individual Single-walled Carbon Nanotubes

单壁碳纳米管（SWCNT）的氧化还原性质（即，电子密度、费米能级、氧化还原电势）与SWCNT的结构有关，所述SWCNT具有与一对整数（n，m）唯一相关的特定直径和手性角;即，即所谓的手性指数。我们已经报道了一种简单的方法，用于确定的氧化和还原电位的孤立单壁碳纳米管的近红外吸收和光致发光光谱电化学与膜含有孤立的单壁碳纳米管。

The redox properties (i.e. electronic densities, the Fermi levels, redox potentials) of single-walled carbon nanotubes (SWCNTs) are related to the structures of SWCNTs that have a specified diameter and chirality angle uniquely related to a pair of ntegers (n,m); i.e., the so-called chiral indices. We have reported a simple method for the determination of the oxidation and reduction potentials of isolated SWCNTs by in situ near-IR absorption and photoluminescence spectroelectrochemistry with a film containing isolated SWCNTs.