Design, synthesis and advanced characterization of functional materials and devices

我们的研究计划旨在推进各种功能半导体材料和异质结构的应用知识，例如(i)压电换能器和能量收集装置，（ii）用于废热回收的热电发电机模块和（iii）用于磁光集成法拉第隔离器的异质薄膜。通过实验、数值和分析方法，我们追求的研究项目提供了晶体生长过程中原子、纳米尺度和界面过程如何最终定义先进材料的大规模功能特性的基本理解。我们的研究通常会导致新的纳米工程薄膜或纳米结构体材料，从根本上改变与工业应用相关的现象。MEMS相关行业需要无铅替代品来取代现有的压电陶瓷，因此我们建议设计和生长基于压电化合物（如ZnO和/或iii -氮化物）的新型合金。电信发射体将受益于集成法拉第隔离器，为此我们建议探索含有磁性纳米团簇的epilayers的增强磁光特性。废热回收将受益于由富含地球元素制成的低重量热电合金，例如Mg2Si，我们已经在我们的实验室中进行了研究，并且需要大幅增加功率因数。****我们计划的目标是建立对控制这些功能材料性质的结构-功能关系的基本理解，特别是磁光和压电现象，以及热能到电能的转换应用。其次，通过将这些基本知识扩展到概念验证设备中，例如热电发电机或法拉第隔离器，我们为开发的材料提供测试。最后，我们已经获得了加拿大计算资源的授权，基于密度泛函理论进行数值计算，以设计具有增强压电和热电性能的新型材料。在我们提出的研究中，我们将受益于这种强大的方法来设计新的合金和化合物，然后将其沉积为薄膜并充分表征。除了可能与材料的机械性能有关外，尚未以系统的方式探索分层结构在引入异质性方面的影响。我们计划的一部分将包括这种新颖的视角，例如在开发ZnO基合金方面。我们的项目将培养从本科生到博士后的高素质人才作为一个重要组成部分。提供的培训经常*涉及国际和本地合作的多学科研究，并与工业界合作。*****

Our research program seeks to advance knowledge on a variety of functional semiconductor- based materials and heterostructures for applications such as (i) piezoelectric transducers and energy harvesting devices, (ii) thermoelectric generator modules for waste heat recovery and (iii) heterogeneous films for magneto optic integrated Faraday isolators. Using experimental, numerical and analytical approaches, the research program we pursue has provided basic understanding of how atomistic, nanoscale and interfacial processes during crystal growth ultimately define large scale functional properties of advancedt materials. Our studies usually lead to new, nanoengineered thin films or nanostructured bulk materials that fundamentally alter phenomena pertinent to industrial applications. MEMS related industries are in need of Pb-free alternatives to replace current piezoelectric ceramics, and so we propose to design and grow novel alloys based on piezoelectric compounds such as ZnO, and/or III-Nitrides. Emitters for telecommunications would profit from integrated Faraday isolators, for which we propose to explore the enhanced magneto optic properties of epilayers containing magnetic nanoclusters. Waste heat recovery will benefit from low-weight thermoelectric alloys made from earth abundant elements, such as Mg2Si, which we are already pursuing in our laboratories and for which a substantial increase in the power factor is necessary.****The objective of our program is to establish a fundamental understanding of structure-function relationships that govern the properties of these functional materials, in particular for magneto optic and piezoelectric phenomena, and thermal to electrical energy conversion applications. Second, by extending this fundamental knowledge into proof of concept devices, such as thermoelectric generators or Faraday isolators, we provide tests for the developed materials where they matter. Finally, we have been granted access to Compute Canada resources for numerical calculations, based on density functional theory, to design novel materials with enhanced piezoelectric and thermoelectric properties. In our proposed research we will profit from this powerful approach to design novel alloys and compounds, which will then be deposited as thin films and fully characterized. The influence of hierarchical structures in the introduction of heterogeneities has not yet been explored in a systematic way, except perhaps in relation to mechanical properties of materials. Part of our program will include this novel perspective, for example in the development of ZnO based alloys. Our program includes as an important component the training of highly qualified personnel from undergraduates to postdoctoral fellows. The training provided frequently*involves multi-disciplinary research under international and local collaborations, and with industry.*****