Interactions of the Cage Compounds ?RA1NR'! with Transition Metal Carbonyl Complexes

笼状化合物“RA1NR”的相互作用！

• 批准号: 8708031
• 负责人: Claire Tessier
• 金额: $ 1.2万
• 依托单位: Case Western Reserve University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1987
• 资助国家: 美国
• 起止时间: 1987-07-01 至 1988-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8708031&HistoricalAwards=false
• 关键词: Interactions; Cage; Compounds; RA1NR; Transition

This award is a Research Planning Grant under the Research Opportunities for Women Program. The research project which will be planned under this grant involves the use of cage-like compounds of aluminum and nitrogen to simulate some of the features of activated metal oxide surfaces which are used as catalyst supports. These cage compounds resemble the surfaces in electronic properties, low coordination number, and multiplicity of active sites. The goal of the research is to induce and characterize multiple interactions of the cage compounds with transition metal carbonyl complexes. The reaction chemistry and photochemistry of the cage-transition metal compounds will be examined. These homogeneous systems will provide interesting contrasts to the chemistry of catalysts composed of transition metal compounds supported on metal oxide surfaces. A better understanding of the relationship between surface effects and the catalytic activity of the heterogeneous species is expected to result from the work.

该奖项是妇女研究机会计划下的研究规划补助金。根据这项拨款计划的研究项目涉及使用铝和氮的笼状化合物来模拟用作催化剂载体的活性金属氧化物表面的一些特征。这些笼状化合物在电子性质、低配位数和活性中心的多样性方面与表面相似。本研究的目的是诱导和表征笼状化合物与过渡金属羰基化合物的多重相互作用。将考察笼状过渡金属化合物的反应化学和光化学。这些均相体系将与由金属氧化物表面负载的过渡金属化合物组成的催化剂的化学组成形成有趣的对比。这项工作有望更好地理解表面效应和多相物种的催化活性之间的关系。