Intercalation of Organic Polymers in Inorganic Layered Materials

9306385 Kanatzidis 在这项工作中，技术上重要的共轭和饱和聚合物插入到层状主机。 对（聚合物）水合五氧化二钒和（聚合物）氯氧化铁的研究将继续更好地了解它们的结构和性能。 提出了深入了解这些材料中的导电聚合物的聚合度的实验。 基于聚合物水合五氧化二钒中n型到p型的转变随x的变化，将研究p-n二极管的特性。 聚苯胺/氯化铁的单晶将通过晶体学分析和电荷传输测量来探索。 在什么构成了一个新的研究方向，新的方法将被开发，包括其他层状主机，这是不适合原位插层氧化还原聚合。 各种新型的共轭聚合物/无机插层化合物将被制备出来。 这些新的主体包括磷酸铀酰、磷酸锆和膦酸锆、氧化铼和过渡金属二硫属化物。 除了共轭聚合物外，饱和聚合物将被用于制备新型的具有层状无机主体的分子尺度纳米复合材料。 提出了这些材料的完整物理化学表征。 ***

9306385 Kanatzidis In the work, technologically significant conjugated and saturated polymers are intercalated into lamellar hosts. Studies on the (polymer) hydrated vanadium pentoxide and (polymer) iron oxychlorides will continue to better understand their structure and properties. Experiments to gain insights into the degree of polymerization of the conductive polymers in these materials are proposed. Based on the n-type to p-type transition which occurs as a function of x in (polymer) hydrated vanadium pentoxide, the behavior of p-n diodes will be studied. Single crystals of polyanaline/iron oxychloride will be explored by crystallographic analysis and charge transport measurements. In what constitutes a new research direction, new methodologies will be developed to include other layered hosts, which are not amenable to in-situ intercalative redox polymerization. A variety of new conjugated polymer/inorganic intercalation compounds will be prepared. These new hosts include uranyl phosphate, zirconium phosphates and phosphonates, molybnenum oxides and transition metal dichalcogenides. In addition to conjugated polymers, saturated polymers will be used to prepare novel molecular scale nano- composites with layered inorganic hosts. A full physico-chemical characterization of these materials is proposed. ***