Mechanistic and Synthetic Studies of New Organic Transformations

本研究的重点是新的酰基锗自由基反应的开发，非对映异构体中间体的基团选择性反应的研究，以及氟双相氢化锡在有机合成中的应用。有了这个更新的奖项，合成有机计划将支持匹兹堡大学化学系的丹尼斯·P·柯伦博士的研究。柯伦教授将把他的工作重点放在为有机合成开发新的自由基反应上。这项研究旨在直接导致环境友好型试剂的发现。

The focus of this research is the development of new radical reactions of acyl germanes, the study of group selective reactions of diastereomeric radical intermediates and the use of fluorous biphasic tin hydrides in organic synthesis. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Dennis P. Curran of the Department of Chemistry at the University of Pittsburgh. Professor Curran will focus his work on the development of new radical reactions for organic synthesis. The research is intended to lead directly to the discovery of environmentally friendly reagents.