Mechanistic and Synthetic Studies of New Organic Transformations

新有机转化的机理和综合研究

• 批准号: 9510345
• 负责人: Dennis Curran
• 金额: $ 40.3万
• 依托单位: University of Pittsburgh
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-07-01 至 1998-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9510345&HistoricalAwards=false
• 关键词: Mechanistic; Synthetic; Studies; New; Organic

The focus of this research is the development of new radical reactions of acyl germanes, the study of group selective reactions of diastereomeric radical intermediates and the use of fluorous biphasic tin hydrides in organic synthesis. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Dennis P. Curran of the Department of Chemistry at the University of Pittsburgh. Professor Curran will focus his work on the development of new radical reactions for organic synthesis. The research is intended to lead directly to the discovery of environmentally friendly reagents.

本研究的重点是开发新的自由基反应 酰基锗烷的基团选择性反应的研究 非对映体自由基中间体和氟双相锡的用途 在有机合成中。 有了这个更新奖，合成有机计划正在支持 丹尼斯博士的研究P. Curran化学系在 匹兹堡大学。 柯伦教授将把他的工作重点放在 有机合成中新的自由基反应的发展。 研究 旨在直接引导人们发现 试剂