Purchase of a CCD-Based X-Ray Diffractometer

该奖项由化学研究仪器和设施 （CRIF）计划将协助大学化学系 加州@尔湾获得一个基于CCD的区域探测器系统， X射线结构分析。该设备将加强研究， 包括以下几个方面：（1）制备低聚物 和聚合配体桥接的过渡金属化合物，（2）合成的 有机镧系元素化学，（3）合成和反应性 倍半硅氧烷，（4）发光和氧化还原活性超分子体系， (5)人工β-折叠的设计、合成和研究，以及（6） 合成有机化学X射线衍射仪是用来使准确和精密 分子的完整三维结构的测量。的 获得的信息给出了所有键距的精确值 和键角的关系，它能给出精确的信息 关于分子相对于相邻分子的空间排列 分子

This award from the Chemistry Research Instrumentation and Facilities (CRIF) Program will assist the Department of Chemistry at University of California@Irvine acquire a CCD-based area detector system for single X-ray structure analysis. This equipment will enhance research in a number of areas including the following: (1) preparation of oligomeric and polymeric ligand-bridged transition metal compounds, (2) synthetic organolanthanide chemistry, (3) synthesis and reactivity of silsesquioxanes, (4) luminescent and redox-active supramolecular systems, (5) design, synthesis, and study of artificial beta-sheets, and (6) synthetic organic chemistry The X-ray diffractometer is used to make accurate and precise measurements of the full three dimensional structure of a molecule. The information obtained gives the precise values of all the bond distances and bond angles of a given molecule and it gives accurate information about the spatial arrangement of the molecule relative to the neighboring molecules