Acquisition of a Supercritical Fluid System for Diverse Undergraduate Curricular Activities

获取用于各种本科课程活动的超临界流体系统

• 批准号: 0127118
• 负责人: William Evans
• 金额: $ 2.93万
• 依托单位: University of California-Irvine
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-01-01 至 2002-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0127118&HistoricalAwards=false
• 关键词: Acquisition; Supercritical; Fluid; System; Diverse

Chemistry (12)Supercritical fluid (SCF) technology is being introduced into the undergraduate curriculum to complement many traditional topics already discussed and to enhance chemical education to prepare students for a variety of work environments. This environmentally-friendly medium is often mentioned only briefly in current undergraduate curricula, usually without any hands-on laboratory experience, even though the diversity of applications involving SCFs continue to mount in virtually every sector of the scientific workplace.A SCF system is being introduced into five different undergraduate chemistry laboratory courses - two analytical, one inorganic, one physical, and one materials courses. Experiments are being adapted primarily from the research literature and implemented into these courses. Analytical experiments are utilizing the system for extraction of analytes from difficult matrices using environmentally-friendly solvents. Inorganic experiments are exploiting the properties of SCFs to isolate novel complexes possessing labile ligands, and other compounds that are traditionally difficult to synthesize/purify. Physical experiments are examining solubility and phase behavior of various co-solvents/SCF mixtures. In addition, thermodynamic and kinetic parameters for a variety of reactions are monitored around the critical point to determine the effects of such media. Semi-empirical and DFT calculations are being carried out to predict speciation within a SCF medium and to compare experimental results. Materials experiments are invoking this technology for polymerization, crystallization, nanoparticle deposition, and thin-film growth applications.

化学（12）超临界流体（SCF）技术正在被引入本科课程，以补充许多已经讨论过的传统主题，并加强化学教育，使学生为各种工作环境做好准备。这种环境友好的介质通常只在当前的本科课程中被简要提及，通常没有任何实际的实验室经验，即使涉及SCF的应用的多样性在科学工作场所的几乎每个部门都在继续增加。实验主要改编自研究文献并实施到这些课程中。分析实验利用该系统使用环境友好的溶剂从困难的基质中提取分析物。无机实验正在利用SCF的性质来分离具有不稳定配体的新型络合物，以及传统上难以合成/纯化的其他化合物。物理实验正在检查各种共溶剂/SCF混合物的溶解度和相行为。此外，在临界点附近监测各种反应的热力学和动力学参数，以确定这种介质的影响。半经验和DFT计算正在进行预测的SCF介质内的形态，并比较实验结果。材料实验正在将这种技术用于聚合、结晶、纳米颗粒沉积和薄膜生长应用。