Collaborative Research: Nanomanufacturing Reduced Graphene Oxide

合作研究：纳米制造还原氧化石墨烯

• 批准号: 1068723
• 负责人: William King
• 金额: $ 7.7万
• 依托单位: University of Illinois at Urbana-Champaign
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-04-01 至 2014-09-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1068723&HistoricalAwards=false
• 关键词: Collaborative; Research; Nanomanufacturing; Reduced; Graphene

This collaborative research award provides funding for understanding and controlling the key factors in the local nanoscale thermal reduction of graphene oxide. In particular, the combination of computational modeling with experiments will give access to the efficiency and rate of the local thermal reduction during the thermochemical nanolithography process, and to the ultimate writing speed and resolution of this technique. The reduced form of graphene oxide (GO) is an attractive alternative to graphene for producing large-scale flexible conductors, supercapacitors, mechanical resonators, and for creating devices that require an electronic gap. Thermochemical nanolithography is a new nanofabrication technique in which heated probe tips can be used to locally control and tune the reduction of GO and pattern nanoscale regions of reduced GO within a GO sheet at speeds of several µm/s, with a resolution of 12 nm. The goal is the transition of this technology to arrays of several cantilevers with hot tips for parallel writing, and the integration of reduced GO nanostructures into field effect transistors prototypes.The research will contribute to elucidate at the atomic-scale the structural properties of GO, the mechanisms driving the reduction process, and the physical-chemical transformations resulting from local heat transfer. This novel understanding will be converted into a modeling scheme to be used to engineering the nano-patterning process. This study will improve the community?s understanding of nanoscale processes and potentially provide inexpensive and robust tools to decrease the cost of nano-manufacturing. Since this project will be developed in close collaboration with an Italian group of the Politecnico of Milano, it will enable exchange of graduate students. In the current climate of outsourcing and globalization of economy, international training is an essential component for the education of our next generation of leaders.

该合作研究奖为理解和控制氧化石墨烯局部纳米级热还原的关键因素提供资金。特别是，计算建模与实验相结合，将获得热化学纳米光刻过程中的局部热还原的效率和速率，以及这种技术的最终写入速度和分辨率。还原形式的氧化石墨烯（GO）是石墨烯的有吸引力的替代品，用于生产大规模柔性导体、超级电容器、机械谐振器，以及用于创建需要电子间隙的设备。热化学纳米光刻是一种新的纳米纤维技术，其中加热的探针尖端可用于局部控制和调节GO的还原，并以几μm/s的速度在GO片内图案化还原GO的纳米级区域，分辨率为12 nm。 我们的目标是将这项技术过渡到具有热尖的多个平行写入的微控制器阵列，并将还原的GO纳米结构集成到场效应晶体管原型中。这项研究将有助于在原子尺度上阐明GO的结构特性，驱动还原过程的机制以及局部热传递引起的物理化学转变。这种新的理解将被转换成一个建模方案，用于工程的纳米图案化过程。 这项研究将改善社区？的理解，并可能提供廉价和强大的工具，以降低纳米制造的成本。由于该项目将与米兰理工大学的一个意大利小组密切合作开发，因此将使研究生交流成为可能。在现时外判及经济全球化的大气候下，国际培训是培育下一代领袖的重要环节。