Boron-functionalized N-heterocycles for stoichiometric and catalytic bond activation

用于化学计量和催化键活化的硼官能化 N-杂环

• 批准号: 218650092
• 负责人: Professor Dr. Matthias Tamm
• 金额: --
• 依托单位: Institut für Anorganische und Analytische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2012
• 资助国家: 德国
• 起止时间: 2011-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/218650092?language=en
• 关键词: Boron; functionalized; heterocycles; stoichiometric; catalytic

Anionic boron-functionalized N-heterocyclic carbenes (NHC) will be synthesized, which carry their negative charge as an intramolecularly bound, weakly coordinating fluoroborate anion (WCA). These WCA-NHC systems will be used for the synthesis of unusual main group and transition metal complexes and will be applied as ancillary ligands in homogeneous catalysis.

将合成阴离子硼官能化的N-杂环卡宾（NHC），其作为分子内结合的弱配位氟硼酸根阴离子（WCA）携带其负电荷。这些WCA-NHC体系将用于合成不寻常的主族和过渡金属配合物，并将在均相催化中用作辅助配体。