MRI: Acquisition of a Variable-Temperature, Dual-Wavelength, Single-Crystal X-Ray Diffractometer
MRI:获取变温、双波长、单晶 X 射线衍射仪
基本信息
- 批准号:1828117
- 负责人:
- 金额:$ 27.97万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2018
- 资助国家:美国
- 起止时间:2018-08-01 至 2021-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award is supported by the Major Research Instrumentation and the Chemistry Research Instrumentation programs. Professor Leonard MacGillivray from University of Iowa and colleagues James Gloer, Christopher Pigge, Gregory Friestad and Scott Daly have acquired a dual source single crystal diffractometer. In general, an X-ray diffractometer allows accurate and precise measurements of the full three-dimensional structure of a molecule, including bond distances and angles, and provides accurate information about the spatial arrangement of a molecule relative to neighboring molecules. The studies described here impact many areas, including organic and inorganic chemistry, materials chemistry and biochemistry. This instrument is an integral part of teaching as well as research and research training of graduate and undergraduate students in chemistry, medicinal chemistry, pharmacy and biochemistry at this institution. It also provides crystallographic services free of charge to faculty and student researchers in primarily undergraduate institutions that do not possess single-crystal X-ray diffractometers in eastern Iowa, western Illinois, and northern Missouri.The proposal is aimed at enhancing research and education at all levels. It especially impacts studies on effects of noncovalent bonding in molecular solids and exploration of templated solid-state reactions. The diffractometer aids the characterization of synthesized compounds using non-innocent ligands, and those having soft-donor ligands with f-elements. The instrument is essential for studies coupling earth-abundant metals with non-innocent ligands to be used in electrochemical carbon dioxide reduction. It is also useful in designing catalytic carbon-hydrogen activation with N-acylhydrazones and for studying reactivity and selectivity in radical polar crossover reactions.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
该奖项由主要研究仪器和化学研究仪器计划支持。来自爱荷华州大学的伦纳德·麦吉利夫雷教授和他的同事詹姆斯·格洛尔、克里斯托弗·皮格、格雷戈里·弗里斯塔和斯科特·戴利获得了一台双源单晶衍射仪。一般来说,X射线衍射仪允许准确和精确地测量分子的完整三维结构,包括键距和角度,并提供关于分子相对于相邻分子的空间排列的准确信息。这里描述的研究影响了许多领域,包括有机和无机化学,材料化学和生物化学。该仪器是该机构化学,药物化学,药学和生物化学研究生和本科生的教学,研究和研究培训的一个组成部分。它还为爱荷华州东部、伊利诺斯州西部和北方密苏里州的没有单晶X射线衍射仪的主要本科院校的教师和学生研究人员免费提供晶体学服务。该提案旨在加强各级的研究和教育。它特别影响了对分子固体中非共价键作用的研究和对模板固态反应的探索。衍射仪有助于使用非无辜配体合成的化合物的表征,以及那些具有含f-元素的软供体配体的化合物。 该仪器对于研究将地球上丰富的金属与非无辜配体偶联用于电化学二氧化碳还原是必不可少的。 该奖项反映了NSF的法定使命,并通过使用基金会的知识价值和更广泛的影响审查标准进行评估,被认为值得支持。
项目成果
期刊论文数量(10)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Opportunities Using Boron to Direct Reactivity in the Organic Solid State
- DOI:10.1055/s-0040-1707297
- 发表时间:2020-10-09
- 期刊:
- 影响因子:2
- 作者:Campillo-Alvarado, Gonzalo;MacGillivray, Leonard R.
- 通讯作者:MacGillivray, Leonard R.
Clues from cocrystals: a ternary solid, polymorphism, and rare supramolecular isomerism involving resveratrol and 5-fluorouracil
共晶体的线索:三元固体、多态性和涉及白藜芦醇和 5-氟尿嘧啶的罕见超分子异构现象
- DOI:10.1039/d0cc08388g
- 发表时间:2021
- 期刊:
- 影响因子:4.9
- 作者:Ortiz-de León, Celymar;MacGillivray, Leonard R.
- 通讯作者:MacGillivray, Leonard R.
Cubane-forming cyclic dienes that exhibit orthogonal reactivities in the solid state
形成古巴烷的环状二烯在固态下表现出正交反应性
- DOI:10.1039/d1cc02725e
- 发表时间:2021
- 期刊:
- 影响因子:4.9
- 作者:Li, Changan;Sinnwell, Michael A.;Swenson, Dale C.;MacGillivray, Leonard R.
- 通讯作者:MacGillivray, Leonard R.
Convenient Syntheses of Trivalent Uranium Halide Starting Materials without Uranium Metal
不含铀金属的三价卤化铀起始材料的便捷合成
- DOI:10.1021/acs.inorgchem.1c00598
- 发表时间:2021
- 期刊:
- 影响因子:4.6
- 作者:Fetrow, Taylor V.;Grabow, J. Peter;Leddy, Johna;Daly, Scott R.
- 通讯作者:Daly, Scott R.
Modifying Phosphorus(III) Substituents to Activate Remote Ligand-Centered Reactivity in Triaminoborane Ligands
修饰磷(III)取代基以激活三氨基硼烷配体中以远程配体为中心的反应性
- DOI:10.1021/acs.organomet.0c00321
- 发表时间:2020
- 期刊:
- 影响因子:2.8
- 作者:Lee, Kyounghoon;Culpepper, Johnathan D.;Parveen, Riffat;Swenson, Dale C.;Vlaisavljevich, Bess;Daly, Scott R.
- 通讯作者:Daly, Scott R.
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Leonard MacGillivray其他文献
Leonard MacGillivray的其他文献
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{{ truncateString('Leonard MacGillivray', 18)}}的其他基金
2018 Crystal Engineering: Progress in Crystal Engineering - Design, Properties, and Function
2018 晶体工程:晶体工程进展 - 设计、特性和功能
- 批准号:
1821514 - 财政年份:2018
- 资助金额:
$ 27.97万 - 项目类别:
Standard Grant
Supramolecular Approaches to Control Reactivity in the Organic Solid State
控制有机固态反应性的超分子方法
- 批准号:
1708673 - 财政年份:2017
- 资助金额:
$ 27.97万 - 项目类别:
Continuing Grant
Templated Solid-State Reactions: Fundamentals to Multiple Reactions
模板化固态反应:多重反应的基础
- 批准号:
1408834 - 财政年份:2014
- 资助金额:
$ 27.97万 - 项目类别:
Continuing Grant
Versatility in Templated Solid-State Reactions
模板化固态反应的多功能性
- 批准号:
1104650 - 财政年份:2011
- 资助金额:
$ 27.97万 - 项目类别:
Continuing Grant
Organic Functional Groups in Templated Solid-State Reactions
模板化固态反应中的有机官能团
- 批准号:
0801329 - 财政年份:2008
- 资助金额:
$ 27.97万 - 项目类别:
Continuing Grant
CAREER: Controlling Solid State Reactivity via Linear Templates
职业:通过线性模板控制固态反应性
- 批准号:
0133138 - 财政年份:2002
- 资助金额:
$ 27.97万 - 项目类别:
Continuing Grant
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