Porous Organic Solid-State Materials for Energy Storage

用于储能的多孔有机固态材料

• 批准号: 2002634
• 负责人: Colin Nuckolls
• 金额: $ 52.5万
• 依托单位: Columbia University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-06-01 至 2023-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2002634&HistoricalAwards=false
• 关键词: Porous; Organic; Solid; State; Materials

Part 1. Non-technical SummaryThis project, which is supported by the Solid State and Materials Chemistry Program in the Division of Materials Research at NSF, combines research and educational objectives to create new types of organic materials to store electrical energy. Energy storage materials, as part of energy storage devices, are critical components in a wide variety of electronic and renewable energy production technologies. Electrochemical processes underpin most electrical energy storage systems such as batteries and capacitors. Organic materials offer unique advantages: they are readily available, and they can be designed and modified to have the required properties. In this project, researchers from Columbia University demonstrate that simple organic dye molecules can be used as tunable building blocks to form these types of energy storage materials. The research provides a fundamental understanding of the relationship between structure and properties relevant for energy storage performance. Insights from this research, may eventually address a key objective in the energy storage field, namely to design materials that combine the high energy density of batteries with the long cycle life and short charging times of capacitors. Additionally, as part of this project a unique hands-on curriculum is developed that focuses on alternative energy and is designed for at-risk students in the local area. Through this outreach program, these students get immediate exposure to the engineering behind solar energy, which will help propel their interest and understanding within STEM.Part 2. Technical SummaryThis project contains three highly integrated Research Objectives: (1) Tuning molecular subunits to control electrochemical behavior; (2) Testing energy storage performances to enhance mechanistic understanding; and (3) Pushing the boundaries of organic materials for improved energy storage related properties. The combination of expertise, working in concert, enables the design, synthesis and study of organic electrode materials in a feedback loop that fosters a holistic understanding and engenders discovery of new properties. This project, which is supported by the Solid State and Materials Chemistry Program in the Division of Materials Research at NSF, creates a new family of organic electron-accepting (n-type) materials for energy storage composed of perylene diimide molecular units covalently linked into three-dimensional architectures using a variety of linkers. The research tests the hypothesis that the structure and electronic properties of perylene diimide architectures can be controlled by coupling complementary molecular building blocks whose chemical characteristics can be used to tune the electrochemical performances of the materials. Additionally, the researchers aim to increase the number of scientists as well as bridge related fields with science through education programs. The coordinated education effort spans K-8 outreach, curriculum development, and research training for undergraduate, graduate, and post-doctoral scientists. As part of this project a unique hands-on curriculum is developed that focuses on alternative energy and is designed for at-risk students in the local area. Through this outreach program, these students get immediate exposure to the engineering behind solar energy, which will help propel their interest and understanding within STEM.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

第1部分。该项目由美国国家科学基金会材料研究部固态和材料化学项目支持，将研究和教育目标结合起来，创造新型有机材料来储存电能。储能材料作为储能装置的一部分，是各种电子和可再生能源生产技术的关键组成部分。电化学过程是大多数电能存储系统（如电池和电容器）的基础。有机材料具有独特的优势：它们容易获得，并且可以设计和修改以具有所需的性能。在这个项目中，来自哥伦比亚大学的研究人员证明，简单的有机染料分子可以作为可调的构建块来形成这些类型的储能材料。该研究对与储能性能相关的结构和性能之间的关系提供了基本的理解。这项研究的见解可能最终解决能源存储领域的一个关键目标，即设计将电池的高能量密度与电容器的长循环寿命和短充电时间结合起来的材料。此外，作为该项目的一部分，我们还开发了一个独特的实践课程，重点关注替代能源，并为当地有风险的学生设计。通过这个外展项目，这些学生可以直接接触到太阳能背后的工程，这将有助于提高他们对STEM的兴趣和理解。第2部分。本项目包含三个高度集成的研究目标：(1)调节分子亚基以控制电化学行为；(2)测试储能性能，增强对机理的理解；(3)推动有机材料的边界，以改善储能相关性能。专业知识的结合，协同工作，使有机电极材料的设计，合成和研究在一个反馈回路中，促进了整体的理解，并产生了新特性的发现。该项目由美国国家科学基金会材料研究部固态和材料化学项目支持，创建了一个新的有机电子接受（n型）材料家族，用于储能，该材料由苝二亚胺分子单元组成，使用各种连接剂共价连接成三维结构。该研究验证了一个假设，即苝二亚胺结构的结构和电子性能可以通过耦合互补的分子构建块来控制，这些分子构建块的化学特性可以用来调节材料的电化学性能。此外，研究人员的目标是增加科学家的数量，并通过教育项目将相关领域与科学联系起来。协调的教育工作涵盖了K-8扩展，课程开发以及本科生，研究生和博士后科学家的研究培训。作为这个项目的一部分，我们开发了一个独特的实践课程，重点是替代能源，并为当地有风险的学生设计。通过这个外展项目，这些学生可以直接接触到太阳能背后的工程，这将有助于提高他们对STEM的兴趣和理解。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

High-Performance Organic Electronic Materials by Contorting Perylene Diimides

• DOI: 10.1021/jacs.1c11544
• 发表时间: 2021-12-23
• 期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
• 影响因子: 15
• 作者: Schaack, Cedric;Evans, Austin M.;Nuckolls, Colin
• 通讯作者: Nuckolls, Colin

Iterative Synthesis of Contorted Macromolecular Ladders for Fast-Charging and Long-Life Lithium Batteries

• DOI: 10.1021/jacs.2c06527
• 发表时间: 2022-07-25
• 期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
• 影响因子: 15
• 作者: Jin, Zexin;Cheng, Qian;Xu, Yunyao
• 通讯作者: Xu, Yunyao

High-performance organic pseudocapacitors via molecular contortion

• DOI: 10.1038/s41563-021-00954-z
• 发表时间: 2021-04-01
• 期刊: NATURE MATERIALS
• 影响因子: 41.2
• 作者: Russell, Jake C.;Posey, Victoria A.;Peurifoy, Samuel R.
• 通讯作者: Peurifoy, Samuel R.