Development of Novel π-Conjugated Systems Based on Porphyrins

我们通过金属配位、温度控制、质子化、分子内融合等多种方法对meso-芳基膨胀卟啉进行了构象控制，获得了较强的4 n π Mobius芳香性。本文报道了一系列新型亚卟啉及其相关分子的合成。此外，我们还发展了一种过渡金属催化的偶联反应来构筑多卟啉阵列。

We have achieved strong 4nπ Mobius aromaticity by various methods for the conformational control of meso-aryl expanded porphyrins, such as metal coordination, temperature control, protonation, and intramoleculer fusion. We report the syntheses of a series of novel subporphyrins and related molecules by various chemical transformations of meso-aryl-subporphyrins. In addition, we have also developed a transition metal-catalyzed coupling reactions toward the construction of multi-porphyrin arrays.