Novel fabrication of fine materials using liquid phase deposition process with Heterogeneous liquid-liquid interface

利用异质液-液界面的液相沉积工艺新型制造精细材料

• 批准号: 19205029
• 负责人: DEKI Shigehito
• 金额: $ 32.12万
• 依托单位: Kobe University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2007
• 资助国家: 日本
• 起止时间: 2007 至 2009
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-19205029/
• 关键词: 液相析出法; 逆相ミセル; 酸化チタン; アナターゼ; ナノ溶液; 異相共存場; 酸化スズ; 酸化物ナノ粒子; 液-液界面; 金属フッ化物; 水溶液内平衡反応; 高分子溶液; 酸化スズナノ粒子; 液-液界面反応; 酸化チタン薄膜; 電位勾配; Ti02(B)

The liquid phase deposition (LPD) of metal oxide thin films at the liquid-liquid interface was investigated. Just after the start of the LPD reaction, depositions were observed continually at the liquid-liquid interface. The deposition grew two-dimensionally into a self-standing film with thickness of 1・m and domain size of up to ca. 1mm without any solid substrates. The self-standing film was formed with asymmetrical morphology, which consisted of flat surface on the side of the liquid-liquid interface and relatively rough surface on the side of the bulk solution. The structure was characterized by Raman spectroscopy, confirming that metastable ammonium titanium oxide fluoride (NH_4TiOF_3) was first deposited at the liquid-liquid interface, on which anatase-type titanium oxide (TiO_2) was deposited second to forming the asymmetrical bilayer structure.

研究了在液-液界面液相沉积金属氧化物薄膜。在LPD反应刚开始后，在液-液界面处连续观察到沉积。沉积层呈二维生长，形成厚度约为1 μ m的自支撑薄膜，畴尺寸约为100 nm。1 mm，无任何固体基质。形成的自支撑膜具有不对称的形貌，其由在液-液界面侧的平坦表面和在本体溶液侧的相对粗糙的表面组成。通过拉曼光谱表征了该结构，证实了在液-液界面首先沉积了亚稳态的氟化钛铵（NH_4TiOF_3），然后在其上沉积了锐钛矿型的二氧化钛（TiO_2），形成了不对称的双层结构。

项目成果

Nanofabrication Process for Highly Orderd Porous Materials by the Liquid Phase Deposition Methods

液相沉积法制备高度有序多孔材料的纳米工艺

• 发表时间: 2008
• 期刊: ECS Transactions 6(11)
• 作者: Jomori;D.;高原淳;Shigehito Deki
• 通讯作者: Shigehito Deki

Liquid phase deposition synthesis of hexagonal molybdenum trioxide thin films

• DOI: 10.1016/j.jssc.2009.06.033
• 发表时间: 2009-09
• 期刊: Journal of Solid State Chemistry
• 影响因子: 3.3
• 作者: S. Deki;A. B. Béléké;Yukinari Kotani;M. Mizuhata

Synthesis of Metal Oxide Nanoparticles in Restricted Space of Perfluorosulfonate Ionomeric Membrane : Nafion(R)

全氟磺酸盐离聚物膜受限空间中金属氧化物纳米颗粒的合成：Nafion(R)

• 发表时间: 2009
• 作者: K. Watanabe;T. Taniguchi;T. Kuroda O. Tsuda;H. Kanda;出来成人
• 通讯作者: 出来成人

液相析出法による希土類系物質の形態制御合成法の開発

液相沉淀法形貌控制合成稀土材料方法的开发

• 发表时间: 2009
• 作者: Y. Fujikawa;T. Sakurai;R. M. Tromp;大井航;Yasuteru Urano;今津隼人・江川貴将・増井敏行・今中信人;Nobuo Kimizuka,;出来成人
• 通讯作者: 出来成人

Continuous Deposition System of SnO2 Thin Film by the Liquid Phase Deposition (LPD) Method

• DOI: 10.2109/jcersj2.115.856
• 发表时间: 2007
• 期刊: Journal of the Ceramic Society of Japan
• 影响因子: 1.1
• 作者: Y. Saito;Yukinari Sekiguchi;M. Mizuhata;S. Deki