Photo-reversible metal-complexation of photo-responsive polymers and quantitative analysis by square-wave voltammetry
Photo-reversible metal-complexation of photo-responsive polymers and quantitative analysis by square-wave voltammetry
批准号:
13555262
负责人:
SUZUKI Takayuki
金额:
$2.5万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2001
资助国家:
日本
项目状态:
已结题
起止时间:
2001 至 2003
中文摘要
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英文摘要
There are no published accounts of photo-reversible metal-complexations that involve an insoluble spiropyran-carrying copolymer in aqueous solutions. Insoluble materials are attractive for metalion adsorption, such as adsorbents or sensors of metals, because of their relative ease of use. Herein, we describe the photoreversible Pb^<2+>-complexation for a synthetic spiropyran methacrylate (SPMA) in polar solvents (mixtures of methanol and water). Furthermore, we present the first demonstration of reversible photo-induced Pb^<2+>-complexation of an insoluble copolymer consisting of SPMA and perfluorooctylhydroxy methacrylate (FHMA), _6P(SPMA-FHMA) aqueous solutions.
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鈴木 隆之: "有機フォトクロミック化合物を用いた金属イオン吸脱着の光制御"表面技術. 53. 659-663 (2002)
Takayuki Suzuki:“使用有机光致变色化合物对金属离子吸附和解吸的光学控制”表面技术 53. 659-663 (2002)。
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鈴木隆之, 河田洋平: "重金属イオンを繰り返し吸脱着する有機フォトクロミック化合物"表面. 41巻・5号. 153-159 (2003)
Takayuki Suzuki、Yohei Kawata:“反复吸附和解吸重金属离子的有机光致变色化合物”Surface,第 41 卷,第 5 期。153-159 (2003)
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鈴木隆之, 篠崎開, 大窪潤, 大野清伍, 柴隆一, 藤本明: "理工系 一般化学"東京教学社. 182 (2002)
Takayuki Suzuki、Kai Shinozaki、Jun Okubo、Seigo Ohno、Ryuichi Shiba、Akira Fujimoto:“科学与工程普通化学”东京京学社 182(2002)。
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T.Suzuki, Y.Kawata, S.Kahata, T.Kato: "Photo-reversible Pb^<2+>-complexation of insoluble poly(spiropyran methacrylate-co-perfluorohydroxy methacrylate) in polar solvents"Chem.Commun.. 2004-2005 (2003)
T.Suzuki、Y.Kawata、S.Kahata、T.Kato:“极性溶剂中不溶性聚(螺吡喃甲基丙烯酸酯-共-全氟羟基甲基丙烯酸酯)的光可逆 Pb^2>-络合”Chem.Commun.. 2004-
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Takayuki Suzuki, Yohei Kawata, Shinsuke Kahata, Tatsuya Kato: "Photo-reversible Pb^<2+>-complexation of insoluble poly(spiropyran methacrylate-co-perfluorohydroxy methacrylate) in polar solvents"Chem.Commun.. 2004-2005 (2003)
Takayuki Suzuki、Yohei Kawata、Shinsuke Kahata、Tatsuya Kato:“极性溶剂中不溶性聚(螺吡喃甲基丙烯酸酯-co-全氟羟基甲基丙烯酸酯)的光可逆 Pb^<2>-络合”Chem.Commun. 2004-2005 (2003)
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