Study on Cooperative Effect Between Metals of Heterodinuclear Organotransition Metal Complex

异双核有机过渡金属配合物金属间协同作用的研究

• 批准号: 21350034
• 负责人: KOMIYA Sanshiro
• 金额: $ 12.31万
• 依托单位: Tokyo University of Agriculture and Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21350034/
• 关键词: ヘテロ二核錯体; 協同効果; 遷移金属錯体; 白金; 遷移金属; パラジウム; 触媒; 有機ヘテロ二核錯体; マンガン; ヒドロメタル化; 配位不飽和種; 二核錯体; 白金-マンガンヘテロ二核錯体; メチル基移動; 可視光

Series of heterodinuclear complexes having a platinum(palladium)-transition metal bond have been prepared and their chemical and catalytic activities are examined. Reversible organic group transfer, enhance CO-insertion, and regio- and stereo-selective ring-opening desulfurization of S-containing small rings are discovered. On the basis of these results, new catalytic reactions such as carbonylation of thietanes and Markovnikov type hydrometallation of transition metal hydrides are developed and their mechanisms are clarified.

合成了一系列铂（钯）-过渡金属键合的异双核配合物，并考察了它们的化学和催化活性。发现了可逆的有机基团转移，增强CO-插入，以及含S小环的区域和立体选择性开环脱硫。在此基础上，发展了硫杂环丁烷的羰基化反应和过渡金属化合物的马氏型加氢反应等新的催化反应，并阐明了它们的反应机理。

项目成果

E-Selective Reactions in Heterodinuclearη^1:η^2-Crotylplatinum-transion MetalComplexes

异双核 η^1:η^2-巴豆基铂-过渡金属配合物中的 E-选择性反应

• 发表时间: 2012
• 作者: Komiya;Sanshiro; Nakano;Toshiki; Saito;Shun; Komine;Nobuyuki; Hirano Masafumi
• 通讯作者: Nobuyuki; Hirano Masafumi

Synthesis and E-Selective Allyl Transfer Reaction of Heterodinuclear Platinum-Group 7 Metal ComplexesHaving a μ-η^1:η^2-Allylic Ligand

具有μ-η^1:η^2-烯丙基配体的异双核铂-7族金属配合物的合成和E-选择性烯丙基转移反应

• 发表时间: 2012
• 作者: Toshiki Nakano;Nobuyuki Komine;Masafumi;Hirano;Sanshiro Komiya
• 通讯作者: Sanshiro Komiya

Synthesis, reaction and catalysis of heterodinuclear organoplatinum or palladium complexes having M-M and M-C bonds without M-M connecting

无M-M连接的具有M-M和M-C键的异双核有机铂或钯配合物的合成、反应和催化

• 发表时间: 2012
• 期刊: Coord.Chem.Rev.
• 作者: Takuya Shiga;Hitoshi Miyasaka;Masahiro Yamashita;Masakazu Morimoto;and Masahiro Irie;Sanshiro Komiya
• 通讯作者: Sanshiro Komiya

Visible light enhanced selective reductive elimination of a methylmanganese complex from a heterodinuclear dimethylphenyl (4, 4'-di-tert-butyl-2, 2'-bipyridine) platinum-pentacarbonylmanganese complex

可见光增强从异双核二甲基苯基（4, 4-二叔丁基-2, 2-联吡啶）铂-五羰基锰络合物中选择性还原消除甲基锰络合物

• 发表时间: 2009
• 期刊: Organometallics 28
• 作者: Sanshiro Komiya;Sei Ezumi;Nobuyuki Komine;Masafumi Hirano
• 通讯作者: Masafumi Hirano

Synthesis and C-S Bond Cleavage Reaction of Bridged and Non-bridged Heterodunuclear Organoplatinum-Manganese Complexes, Frtontiers of Organometallic Chemistry

桥联和非桥联异双核有机铂锰配合物的合成和C-S键断裂反应，有机金属化学前沿

• 发表时间: 2012
• 作者: Junya Ohyama;Kentaro Teramura;Yasuhiro Higuchi;Tetsuya Shishido;Yutaka Hitomi;Kazuo Kato;Hajime Tanida;Tomoya Uruga;and Tsunehiro Tanaka;山本陽介;Sanshiro Komiya
• 通讯作者: Sanshiro Komiya