Development of Novel Amphiphilic Polymers for the Promotion of Oxidation Reactions in Aqueous Media

设计并合成了新型两亲性交联聚苯乙烯基共聚物，在共聚物的接枝链上引入了羰基。这些共聚物树脂作为反应位点，在水中能有效地促进各种烯烃在聚合物基质中的过硫酸氢钾环氧化反应。确定了共聚物的最佳结构和最佳反应条件。通过本研究项目，我们可以为水介质中的氧化反应提出新的高度安全的方法。

New amphiphilic cross-linked polystyrene-based copolymersbearing carbonyl groups in the grafted chains of the copolymers were designed andprepared. These copolymer-resins were significantly effective as reaction sites to promotethe epoxidation reactions of various alkenes by Oxone inside their polymer matrices inwater. The optimum structure of the copolymers and the optimum reaction conditions wereestablished. Through this research project, we can propose new highly secure methodologyfor oxidation reaction in aqueous media.