Developments of environmentally-benign C-C bond formation reactions via C-O bond cleavage

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(1) The first cross-coupling between organozincate and aryl ether via cleaving etheric C-O bond was achieved. Some of the results were publised in Chem. Eur. J. and was highlighted in SYNFACTAS as "SYNFACTS of the month". (2) The first transition-metal-ctalyst-free cross-coupling between organozinc reagent and oeganic halide was accomplished. Some of the results were publised in Eur. J. Org. Chem. (3) Mechanistic investigations for several important organic reactions were successfully performed by using computational and theoretical methods. Some of the results were publised in Eur. J. Org. Chem., J. Am. Chem. Soc., etc.