Materials Science of Metal Complex Arrays

我们主要从蛋白质结构科学的角度研究了与构建金属络合物阵列三维结构相关的课题，目的是更深入地了解金属络合物阵列的二级结构，并开发使多个二级结构耦合的方法。通过研究我们发现，与相应的同金属序列相比，异质金属序列可以稳定金属络合物阵列的螺旋构象。此外，我们还成功地建立了一种新的合成方法，用于构建分子量与小蛋白相当的顺序控制的金属络合物阵列。

We investigated the subjects related with the construction of 3D structures of metal complex arrays mainly from protein structural science point of view, where the targets were to gain deeper insights on their secondary structures and to develop the methods to make multiple secondary structures couple. Through the researches we found that a heteremetallic sequence can stabilize a helical conformation of the metal complex arrays compared with the corresponding homometallic sequences. Moreover, we also successfully established a new synthetic approach for the construction of sequence-controlled metal complex arrays that have molecular weights comparable to small proteins.