A Novel Instrument for Characterising the Properties and Processes of Single Accumulation Mode Aerosol Particles

表征单累积模式气溶胶颗粒性质和过程的新型仪器

• 批准号: NE/H001972/1
• 负责人: Jonathan Reid
• 金额: $ 32.21万
• 依托单位: University of Bristol
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2010
• 资助国家: 英国
• 起止时间: 2010 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=NE%2FH001972%2F1
• 关键词: Novel; Instrument; Characterising; Properties; Processes

The influence of aerosols and clouds remains one of the largest uncertainties in modelling previous variabilities in climate and in predicting future climate change. In addition, airborne particulates have been shown to have a significant impact on human morbidity and mortality, influence quality of life and impact on atmospheric visibility. A better quantification of the processes that regulate the properties of particles in the atmosphere is central to improve our understanding of their impact. A considerable amount of information can be gained about aerosols by measuring the size, composition and properties of particles found in the atmosphere through large scale field campaigns. However, there remain a number of key fundamental uncertainties that need addressing before our understanding of atmospheric aerosol can become more fully refined. In particular, considerable uncertainty remains in our understanding of the thermodynamic, kinetic and optical parameters that govern aerosol properties. Controlled laboratory measurements can allow us to address some of these key uncertainties directly in a manner that is not possible from field measurements. Conventional laboratory strategies for tackling these challenges are frequently complicated by the inherent averaging that occurs when measurements are made on ensembles of particles, are compromised by an inability to characterise all of the key parameters defining the system, and are unable to cover the timescales relevant to aerosol found in the atmosphere. This project will seek to establish a new paradigm for investigating the thermodynamic, kinetic and optical parameters governing the properties of atmospheric aerosol. Specifically, a novel light trapping technique will be used to capture and manipulate single sub-micron particles, the size range particularly relevant to atmospheric aerosol, over indefinite timescales. This will be combined with an ultrasensitive technique for probing the size and composition of the captured aerosol with high time resolution, leading to the development of a novel prototype instrument for investigating the properties of single particles. The new instrument will immediately be used to address three of the key uncertainties in understanding aerosol. Firstly, the kinetic factors governing the growth rate of particles through the adsorption of water from the gas phase will be investigated. This study will be the first ever direct measurement of the size changing dynamics recorded on a single sub-micron particle. Secondly, the activation of a single accumulation mode particle under supersaturated conditions will be investigated, allowing a detailed investigation of the factors than limit or facilitate the activation of cloud condensation nuclei without the ambiguity that often arises from inhomogeneity in aerosol sample composition and ensemble averaging. Finally, the optical properties of single accumulation mode particles will be investigated, providing a rigorous test of the modelling approaches used to simulate the light scattering properties of aerosol in the atmosphere, their dependence on particle size and composition, and the influence of component mixing state. Performing the studies outlined above on single accumulation mode particles will provide a novel and timely approach to address some of the challenges in interpreting the properties and processes occurring on atmospheric aerosol.

气溶胶和云的影响仍然是对以往气候变化进行建模和预测未来气候变化的最大不确定性之一。此外，空气中的颗粒物已被证明对人类发病率和死亡率有重大影响，影响生活质量，并影响大气能见度。更好地量化调节大气中颗粒物特性的过程，对于提高我们对它们影响的理解至关重要。通过大规模实地活动测量大气中发现的颗粒物的大小、组成和性质，可以获得关于气溶胶的大量信息。然而，仍然有一些关键的基本不确定性，需要解决之前，我们对大气气溶胶的理解可以得到更充分的完善。特别是，相当大的不确定性仍然存在于我们的理解的热力学，动力学和光学参数，支配气溶胶的属性。受控的实验室测量可以让我们以现场测量不可能的方式直接解决其中一些关键的不确定性。应对这些挑战的传统实验室策略经常由于对粒子集合进行测量时发生的固有平均而变得复杂，由于无法确定定义系统的所有关键参数而受到损害，并且无法涵盖与大气中发现的气溶胶相关的时间尺度。该项目将寻求建立一种新的模式，用于研究控制大气气溶胶性质的热力学、动力学和光学参数。具体来说，一种新的光捕获技术将用于捕获和操纵单个亚微米颗粒，尺寸范围特别与大气气溶胶相关，在无限的时间尺度。这将与一种超灵敏技术相结合，以高时间分辨率探测捕获的气溶胶的大小和组成，从而开发出一种新型原型仪器，用于研究单个颗粒的性质。新仪器将立即用于解决理解气溶胶的三个关键不确定性。首先，将研究通过从气相中吸附水来控制颗粒生长速率的动力学因素。这项研究将是有史以来第一次直接测量记录在单个亚微米颗粒上的尺寸变化动态。其次，将研究在过饱和条件下单个累积模式粒子的激活，允许详细研究限制或促进云凝结核激活的因素，而不存在气溶胶样品成分和集合平均的不均匀性所引起的模糊性。最后，将研究单一累积模式粒子的光学特性，对用于模拟大气中气溶胶的光散射特性的建模方法进行严格测试，测试其对粒子大小和组成的依赖性，以及组分混合状态的影响。对单一累积模式粒子进行上述研究将提供一种新颖和及时的方法，以解决解释大气气溶胶特性和过程中的一些挑战。

项目成果

Angular scattering of light by a homogeneous spherical particle in a zeroth-order Bessel beam and its relationship to plane wave scattering.

• DOI: 10.1364/josaa.32.001053
• 发表时间: 2015-06
• 期刊: Journal of the Optical Society of America. A, Optics, image science, and vision
• 作者: T. Preston;J. Reid

Accurate Measurement of the Optical Properties of Single Aerosol Particles Using Cavity Ring-Down Spectroscopy.

• DOI: 10.1021/acs.jpca.2c01246
• 发表时间: 2022-05-05
• 期刊: The journal of physical chemistry. A
• 作者: Cotterell MI;Knight JW;Reid JP;Orr-Ewing AJ
• 通讯作者: Orr-Ewing AJ