STRUCTURE OF TRANSITION METAL COMPLEXES BY ESR

这个子项目是利用资源的许多研究子项目之一。 由NIH/NCRR资助的中心拨款提供。对子项目的主要支持 子项目的首席调查员可能是由其他来源提供的， 包括美国国立卫生研究院的其他来源。为子项目列出的总成本可能 表示该子项目使用的中心基础设施的估计数量， 不是由NCRR赠款提供给次级项目或次级项目工作人员的直接资金。 Wolczanski教授(Cornell)对过渡金属络合物的合成、反应活性和应用感兴趣。使用空间大的配体(例如，Silox(TBu3SiO)，tBu3SiNH，tBu3SiN和tritox(TBu3CO))，他们探索了裂解CX(X=H，C，杂原子)键的低配位金属中心的反应性。ESR可以提供重要的结构信息，并能深入了解配体参与金属键的程度。

This subproject is one of many research subprojects utilizing the resources provided by a Center grant funded by NIH/NCRR. Primary support for the subproject and the subproject's principal investigator may have been provided by other sources, including other NIH sources. The Total Cost listed for the subproject likely represents the estimated amount of Center infrastructure utilized by the subproject, not direct funding provided by the NCRR grant to the subproject or subproject staff. The Prof. Wolczanski group (Cornell) is interested in the synthesis, reactivity and applications of transition metal complexes. Using sterically bulky ligands (e.g, silox(tBu3SiO), tBu3SiNH, tBu3SiN and tritox (tBu3CO)), they explore the reactivity of low coordinate metal centers that cleave CX (X = H, C, heteroatom) bonds. ESR can provide important structural information and give insight into the extend of ligand participation into metal bonding.