Single Atom Catalysts and Atomic Scale Design of Interface for Electrochemical Energy Conversion and Storage

越来越多的人意识到纳米技术将对能源的产生和储存产生深远的影响。孙博士将继续利用他在纳米技术方面的专业知识来解决燃料电池和固态锂电池的关键挑战，但在接下来的六年里，他的工作将在本提案中强调从纳米尺度到原子尺度的更小尺度。****这个提议的目标是领导一个强有力的研究计划，建立在原子层沉积（ALD）和分子层沉积（MLD）技术的能源应用。本提案涵盖两个主题的基础研究：(i)单原子材料作为质子交换膜（PEM）燃料电池的新型催化剂；（二）下一代全固态电池界面的原子尺度设计与工程。一个重要的方面是应用各种先进的表征技术（包括原位/operando）来进行基本的理解。“探索研究基金”支持基础研究和基础科学，而孙博士的其他基金则支持更多的应用研究和实际应用。****对于PEM燃料电池来说，成本和耐用性是PEMFC系统在经济上可行之前必须克服的两个主要障碍。Pt基的成本仍然占燃料电池成本的很大比例，但Pt仍然是燃料电池中最好的催化剂。因此，开发一种低成本和稳定的超低铂负载催化剂将为我们提供减少成本和性能差距的手段，以实现商业可行性。单原子催化剂是一种很有前途的选择，但其合成的可控性和稳定性有待进一步研究。该领域的两个具体目标包括：(i) ALD合成单原子或簇pt基催化剂，以及（ii）通过设计稳定剂和催化剂的支撑来稳定单原子催化剂。单原子催化剂具有较高的催化性能、较高的催化剂利用率、较高的耐久性和较长的燃料电池使用寿命，有望成为理想的材料。****所有固态电池（SSBs）最近吸引了比以往更多的研究和工业兴趣。SSBs的优点是更安全、能量密度更高。然而，在ssb中仍然存在一些关键的挑战，包括界面问题和金属保护。两个具体目标是：(i)稳定固态锂电池电极和电解质之间的界面；（ii）所有固态电池的Li/Na金属保护。预计该项目的成果将有助于生产稳定和长寿命的固态电池。****该计划的成功完成将通过加速燃料电池和固态电池的商业化进程，同时减少环境污染，从而有利于加拿大工业和全球纳米技术社区。******

There is a growing awareness that nanotechnology will have a profound impact on energy generation and storage. Dr. Sun will continue to use his expertise in nanotechnology to address critical challenges in fuel cells and solid-state Li batteries but, in next six year, his work will highlight even smaller scales from nano scale to atomic scale in this proposal.**** The objective of this proposed proposal is to lead a vigorous research program that builds on atomic layer deposition (ALD) and molecular layer deposition (MLD) techniques for energy applications. This proposal covers fundamental studies in two themes: (i) single atom materials as novel catalyst for proton exchange membrane (PEM) fuel cells; and (ii) atomic scale design and engineering of interface for next-generation all solid-state batteries. An important aspect is to apply various advanced characterization techniques (including in-situ/operando) for the fundamental understanding. The Discovery Grant (DG) supports fundamental studies and basic science while Dr. Sun's other funding supports more applied studies and practical applications.**** For PEM fuel cells, cost and durability are two major roadblocks that have to be overcome before the PEMFC system can become economically viable. The cost of Pt-based still accounts for a big percentage of the cost of fuel cells but Pt is still the best catalysts in fuel cells. Therefore, the development of a low cost and stable catalyst with ultra-low Pt loading will provide us the means to reduce the cost and performance gaps towards commercial viability. Single atom catalyst is a very promising choice but its controllable synthesis and stability need to be well addressed. The two specific objectives in this area include: (i) synthesis of single-atom or cluster Pt-based catalysts by ALD, and (ii) stabilization of single atom catalyst by design of stabilizers and support of the catalysts. It is expected that the single atom catalysts will be ideal materials for providing a higher catalytic performance, high catalyst utilization, high durability, and a longer fuel cell operational life.**** All solid-state batteries (SSBs) have been attracting more than ever research and industrial interests recently. The advantages of SSBs are safer and higher energy density. However, there are still some key challenges including interfacial issues and metal protections in SSBs. The two specific objectives are: (i) stabilizing the interface between electrodes and electrolytes for solid-state Li batteries; and (ii) protection of Li/Na metals for all solid-state batteries. It is expected that the outcome of this project will go towards aiding the production of stable and long-life solid-state batteries.**** The successful completion of the program will be of benefit to Canadian industry, and to the global nanotechnology community by accelerating the fuel cell and solid-state battery commercialization process while simultaneously reducing environmental pollution.******