Solid-state NMR methods for the study of the properties and spatial distribution of anchored metal complexes in porous solids (C01+)

本项目重点研究新型固态核磁共振探针分子的开发和应用，用于测定锚定在三维载体材料孔隙内的分子催化剂的空间分布，用原位核磁共振方法测定固定化分子催化剂的中间体、反应机理和反应动力学，以及用脉冲场梯度核磁共振（PFG NMR）研究多孔载体内模型反应物的输运性质。这些研究结果将极大地支持高活性和选择性催化剂的开发以及所研究的反应体系的建模。

This project focuses on the development and application of novel solid-state NMR probe molecules for the determination of the spatial distribution of molecular catalysts, anchored inside the pores of three-dimensional support materials, the determination of intermediates, reaction mechanisms, and reaction kinetics at immobilized molecular catalysts by in situ NMR methods, and the study of transport properties of model reactants inside porous supports by pulsed-field gradient NMR (PFG NMR). The results of these investigations will significantly support the development of highly active and selective catalysts and the modelling of the reaction systems under study.