Approach using reactor design to suppress a deep oxidation in the oxidative dehydrogenation of propane over solid catalysts
Approach using reactor design to suppress a deep oxidation in the oxidative dehydrogenation of propane over solid catalysts
批准号:
21656210
负责人:
SUGIYAMA Shigeru
金额:
$2.16万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Challenging Exploratory Research
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011
中文摘要
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英文摘要
A microreactor was employed for the oxidative dehydrogenation of propane to propylene in order to suppress a deep oxidation of the resultant propylene to CO and CO_2. The enhancement of the selectivity to propylene was the most advantageous effect from using the microreactor, and it occurred when calcium hydroxyapatite was used under an unsteady-state on reaction temperature. For example, the selectivity to propylene was 0 and 73. 0% using a fixed-bed continuous-flow reactor and the microreactor, respectively, under almost identical propane conversion of 3. 1 and 3. 2%, respectively.
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プロパンの接触酸化脱水素用マイクロリアクタに対する最適触媒の探索
丙烷催化氧化脱氢微反应器最佳催化剂的探索
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Sugiyama S, et al., 杉山茂・古川幸美・米田沙織・杉本直登・中川敬三・外輪健一郎]
通讯作者:
杉山茂・古川幸美・米田沙織・杉本直登・中川敬三・外輪健一郎
アパタイトの特異触媒活性と接触型マイクロリアクタを用いた省資源化の試み
利用磷灰石独特的催化活性和接触式微反应器尝试节约资源
DOI:
--
发表时间:
2011
期刊:
セラミックス
影响因子:
--
作者:
[多湖輝興・吉川琢也・増田隆夫, 杉山茂]
通讯作者:
杉山茂
Highly Selective Production of Propylene from the Oxidative Dehydrogenation of Propane on Hydroxyapatite Using Microreactor
微反应器羟基磷灰石上丙烷氧化脱氢高选择性生产丙烯
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[Sugiyama S, et al.]
通讯作者:
et al.
固体触媒によるプロパン酸化脱水素反応の完全酸化抑制に対するマイクロリアクタの応用
应用微反应器完成固体催化剂丙烷氧化脱氢反应的氧化抑制
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Sugiyama S, et al., 杉山茂・古川幸美・米田沙織・杉本直登・中川敬三・外輪健一郎, 杉山茂, 杉山茂]
通讯作者:
杉山茂
触媒調製ハンドブック第2編金属酸化物触媒第3章複合酸化物第5節ヒドロキシアパタイト
催化剂制备手册第 2 部分金属氧化物催化剂第 3 章复合氧化物第 5 节羟基磷灰石
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[杉山茂, 他, 杉山茂]
通讯作者:
杉山茂
共 14 条
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Japan's shrimp trawl fisheries in the Gulf of California and the trilateral relations between Japan, Mexico, and the United States in the 1930s
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