Study towards nitrene transfer reaction using azide based on design of new iron catalyst

在工作假设的基础上设计了一系列新的配体，并按原计划建立了合成方法，制备了一些金属配合物。虽然使用叠氮化物作为氮烯源的氮烯转移反应的有效催化剂目前还没有发现，但在本研究中发现一些络合物作为有氧氧化的催化剂。另一方面，建立了一种将胺官能团氧化引入烯烃的新方法。

A synthetic method for a new series of ligands, which were designed based on a working hypothesis, has been established as originally planned, and some metal complexes were prepared. Although an efficient catalyst for a nitrene transfer reaction using azide as a nitrene source could not be found at this moment, it was found that some complexes worked as catalysts for aerobic oxidation during this study. On the other hand, a new method for oxidative introduction of an amine functionality into olefins was established.