Developments of environmentally-benign C-C bond formation reactions via C-O bond cleavage

(1)首次实现了有机锌与芳基醚通过断裂醚基C-O键的交叉偶联。部分研究结果发表在《化学》杂志上。欧元。J.并在SYNFACTAS中被突出显示为“本月最佳SYNFACTS”。(2)首次实现了有机锌试剂与有机卤化物的无过渡金属交叉偶联。其中一些结果以欧元发布。J.组织化学。(3)用计算和理论相结合的方法对几个重要的有机反应进行了力学研究。其中一些结果以欧元发布。J.组织化学，J.Am化学。SOC等。

(1) The first cross-coupling between organozincate and aryl ether via cleaving etheric C-O bond was achieved. Some of the results were publised in Chem. Eur. J. and was highlighted in SYNFACTAS as "SYNFACTS of the month". (2) The first transition-metal-ctalyst-free cross-coupling between organozinc reagent and oeganic halide was accomplished. Some of the results were publised in Eur. J. Org. Chem. (3) Mechanistic investigations for several important organic reactions were successfully performed by using computational and theoretical methods. Some of the results were publised in Eur. J. Org. Chem., J. Am. Chem. Soc., etc.