STRUCTURE OF TRANSITION METAL COMPLEXES BY ESR

这个子项目是许多研究子项目中的一个 由NIH/NCRR资助的中心赠款提供的资源。子项目和 研究者（PI）可能从另一个NIH来源获得了主要资金， 因此可以在其他CRISP条目中表示。所列机构为 研究中心，而研究中心不一定是研究者所在的机构。 Wolczanski教授小组（康奈尔大学）对过渡金属配合物的合成，反应性和应用感兴趣。 使用空间体积大的配体（例如，silox（tBu 3SiO）、tBu 3SiNH、tBu 3SiN和tritox（tBu 3CO）），他们探索了切割CX（X = H、C、杂原子）键的低配位金属中心的反应性。ESR可以提供重要的结构信息，并深入了解配体参与金属成键的程度。

This subproject is one of many research subprojects utilizing the resources provided by a Center grant funded by NIH/NCRR. The subproject and investigator (PI) may have received primary funding from another NIH source, and thus could be represented in other CRISP entries. The institution listed is for the Center, which is not necessarily the institution for the investigator. The Prof. Wolczanski group (Cornell) is interested in the synthesis, reactivity and applications of transition metal complexes. Using sterically bulky ligands (e.g, silox(tBu3SiO), tBu3SiNH, tBu3SiN and tritox (tBu3CO)), they explore the reactivity of low coordinate metal centers that cleave CX (X = H, C, heteroatom) bonds. ESR can provide important structural information and give insight into the extend of ligand participation into metal bonding.