High Resolution of NMR of Reverse Micelles in Supercritical Fluids

这个妇女职业发展研究机会奖项目是在分析化学和表面化学的一般领域以及分离科学和超临界流体的子领域。在1989年5月1日开始的12个月期间，Olesik教授将进行一系列高分辨率核磁共振实验，研究超临界流体中反胶束和溶质分子之间的分子相互作用。具体来说，她将确定AOT反胶束系统的各种特性，并探索溶质在非极性液体和超临界流体中在超过5000 psi压力下的行为。该职业发展奖将使Olesik教授能够扩展她的研究能力，包括使用高分辨率核磁共振作为分子探针。这项研究的结果可能在分析化学的各个领域产生广泛的影响，特别是在色谱和质谱方面。

This Research Opportunities for Women Career Advancement Award project is in the general area of analytical and surface chemistry and in the subfields of separations science and supercritical fluids. During the twelve month period beginning 1 May 1989, Professor Olesik will undertake a series of high resolution nuclear magnetic resonance (NMR) experiments in which she will investigate the molecular interactions between reverse micelles and solute molecules in supercritical fluids. Specifically, she will determine various properties of the AOT reverse micelle system and explore the behavior of solutes in both nonpolar liquids and supercritical fluids at pressures above 5,000 psi. This Career Advancement Award will enable Professor Olesik to expand her research capabilities to include the use of high resolution NMR as a molecular probe. The results of this research could impact broadly in various areas of analytical chemistry, particularly in chromatography and mass spectrometry.