Platinum Silyl Complexes as Reactive Intermediates for the Catalytic Hydrogenolysis of Disilanes

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One aim of this research project is the development of catalytic processes for the hydrogenolysis of Si-Si bonds at platinum complexes. In order to gain a better understanding of the catalytic mechanisms, conceivable intermediates will be synthesized by model studies, and the reactivity of these compounds will be investigated. In addition, it is envisaged to cleave Si-O bonds of alkoxydisilanes by hydrodealkoxylation, which will pave a way to SiH3, alkoxysilyl, and dialkoxysilyl building blocks, which can subsequently be utilized for Si-C coupling reactions.