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Activation of C-H and C-F bonds at rhodium complexes for the functionalization of fluorinated olefins and ethers

Activation of C-H and C-F bonds at rhodium complexes for the functionalization of fluorinated olefins and ethers
铑配合物中 C-H 和 C-F 键的活化，用于氟化烯烃和醚的官能化
批准号：
461089492
负责人：
Professor Dr. Thomas Braun
金额：
$0.0万
依托单位：
Arbeitsgruppe Organometallchemie und homogene Katalyse
依托单位国家：
德国
项目类别：
Research Grants
财政年份：
--
资助国家：
德国
项目状态：
未结题
起止时间：
来源：
https://gepris.dfg.de/gepris/projekt/461089492?language=en
关键词：
Activationbondsrhodiumcomplexesfunctionalization

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英文摘要
The proposal deals with the activation of C-H and C-F bonds in fluorinated olefins and ethers at the rhodium complexes Rh(R)(PEt3)3] (R = Si(OEt)3, GePh3, Bpin). Based on mechanistic studies borylation, germylation, silylation and dehydrofluorination reactions will be developed. Based on the stoichiometric model reactions, the development of catalytic processes is envisaged.
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