Polysulfonic acids and polysulfonates: Synthesis, structures, and properties

聚磺酸和聚磺酸盐：合成、结构和性能

• 批准号: 223676145
• 负责人: Professor Dr. Jens Christoffers
• 金额: --
• 依托单位: Institut für Chemie (IfC)
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2012
• 资助国家: 德国
• 起止时间: 2011-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/223676145?language=en
• 关键词: Polysulfonic; acids; polysulfonates; Synthesis; structures

The project is the continuation of our work on polysulfonic acids. These acids are the sulfo-analogs of the well-known polycarboxylic acids. In contrast to the latter very little is known about the synthesis of of polysulfonic acids, their properties, and their salts. This collaborative project combines the expertise of an organic chemistry group (Christoffers) and an inorganic chemistry group (Wickleder). The Christoffers group develops new preparative pathways to polysulfonic acids, while the Wickleder group prepares the salts of these acids (polysulfonates) by various methods. The compounds obtained will be structurally characterized by means of X-ray diffraction, as well as by NMR and vibrational spectroscopy. The great diversity in the scaffolds of the organic acids will be used to create linkages of different dimensionality (chains, layers, networks) in the structures of the polysulfonates. Moreover, the nature of the implemented metals will lead to further properties. Of special interest is the magnetic behaviour (transition metals) and the luminescence (rare earth metals) of the prepared compounds.

该项目是我们在聚磺酸方面工作的延续。这些酸是众所周知的多元羧酸的磺基类似物。与后者相反，人们对多磺酸的合成、其性质及其盐知之甚少。该合作项目结合了有机化学小组（Christoffers）和无机化学小组（Wickleder）的专业知识。 Christoffers 小组开发了多磺酸的新制备途径，而 Wickleder 小组则通过各种方法制备这些酸的盐（多磺酸盐）。所得化合物将通过X射线衍射、NMR和振动光谱进行结构表征。有机酸支架的巨大多样性将用于在聚磺酸盐结构中创建不同维度（链、层、网络）的连接。此外，所使用的金属的性质将带来更多的性能。特别令人感兴趣的是所制备的化合物的磁性行为（过渡金属）和发光（稀土金属）。

项目成果

Pyridine and Pyrimidine Functionalized Benzene Sulfonic and Disulfonic Acids as New Linker Compounds for Coordination Polymers

吡啶和嘧啶官能化苯磺酸和二磺酸作为配位聚合物的新型连接化合物

• DOI: 10.1002/ejoc.201801184
• 发表时间: 2018
• 期刊: European Journal of Organic Chemistry
• 影响因子: 2.8
• 作者: C. Kahrs;M. Schmidtmann;M. S. Wickleder;J. Christoffers
• 通讯作者: J. Christoffers

Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}

三核配合物 {Ni3[CH(SO3)3]2(NMP)8} 中的三脚甲三磺酸盐配体

• DOI: 10.1515/znb-2018-0152
• 发表时间: 2019
• 期刊: Zeitschrift für Naturforschung B
• 作者: M. Gudenschwager;J. Christoffers;M. S. Wickleder
• 通讯作者: M. S. Wickleder

Carboxylate Groups in a 90° Arrangement: 1,3-Allenedicarboxylic Acid and Its Alkali Metal and Thallium(I) Coordination Compounds

• DOI: 10.1002/ejic.201900520
• 发表时间: 2019-06-16
• 期刊: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
• 影响因子: 2.3
• 作者: Kahrs, Christoph;Schmidtmann, Marc;Christoffers, Jens
• 通讯作者: Christoffers, Jens

Synthesis of Aromatic and Aliphatic Di-, Tri-, and Tetrasulfonic Acids

芳香族和脂肪族二磺酸、三磺酸和四磺酸的合成

• DOI: 10.1055/s-0039-1691745
• 发表时间: 2020
• 期刊: Synlett
• 影响因子: 2
• 作者: J. Christoffers;M. S. Wickleder
• 通讯作者: M. S. Wickleder

Biphenyl Sulfonic and Disulfonic Acids with Perfluorinated Alkyl Residues

• DOI: 10.1002/ejoc.201800882
• 发表时间: 2018-10
• 期刊: European Journal of Organic Chemistry
• 影响因子: 2.8
• 作者: Christoph Kahrs;M. Wickleder;J. Christoffers