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Creation of metal complexes and their assemblies causing multi-mode reversible conversion of structures and physical properties

Creation of metal complexes and their assemblies causing multi-mode reversible conversion of structures and physical properties
金属络合物及其组装体的产生导致结构和物理性质的多模式可逆转换
批准号:
20245013
负责人:
NISHIHARA Hiroshi
金额:
$30.78万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (A)
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2010

项目摘要

项目成果

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中文摘要
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英文摘要
This study aims at creation of metal complexes and their assemblies which undergo reversible and multiple mode conversion of structures and physical properties. In this study, it is expected to induce multiple stabilities not only by analyzing the physical properties of the molecules but also by operating the bonding nature of the molecules, and to find unique chemical bond formation from the molecules with unprecedented electronic structures. Redox-conjugated photochromic molecules, pyrylinium-containing fused ring compounds with strong intramolecular donor-acceptor interaction, metalladitholenes with photo-, magneto-, and electro-functions and their-extended systems were developed.
期刊论文(235)
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会议论文
DOI: 10.1021/ja105250f
发表时间: 2010-09-08
期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
影响因子: 15
作者: [Rao, Koya Prabhakara, Kusamoto, Tetsuro, Nishihara, Hiroshi]
通讯作者: Nishihara, Hiroshi
Switching of Molecular Insertion in a Cyclic Molecule via Photo- and Thermal Isomerization
通过光异构化和热异构化切换环状分子中的分子插入
DOI: 10.1021/ic200145h
发表时间: 2011
期刊: Inorg. Chem.
影响因子: 4.6
作者: [Satoshi Umeki, Shoko Kume, Hiroshi Nishihara]
通讯作者: Hiroshi Nishihara
DOI: 10.1021/ic202548g
发表时间: 2012-01
期刊: Inorganic chemistry
影响因子: 4.6
作者: [Satoru Tsukada;Y. Shibata;R. Sakamoto;Tetsuya Kambe;T. Ozeki;H. Nishihara]
通讯作者: Satoru Tsukada;Y. Shibata;R. Sakamoto;Tetsuya Kambe;T. Ozeki;H. Nishihara
複数の金属-金属結合とπ共役による強い核間相互作用を有した9核ジチオレンクラスター錯体
由于多个金属-金属键和π共轭而具有强核间相互作用的九核二硫醇簇配合物
DOI: --
发表时间:
期刊:
影响因子: --
作者: [河原一文, 長田師門, 新井貴子, 山田紘理, 黒田一幸, 塚田 学,神戸 徹也,坂本 良太,西原 寛]
通讯作者: 塚田 学,神戸 徹也,坂本 良太,西原 寛
193
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    • 资助金额:
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    • 财政年份:
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