Synthesis of Bimetallic Complexes Activated by Tridentate Ligands

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On the basis of Concerto Catalysis, new types of tridentate nitrogen-based ligands have been developed to show high catalytic activities in the combination of rhodium and ruthenium atoms. The catalysts exhibited high efficiencies in product and optical yields for reduction- or C-H bond activation based asymmetric carbon bond formations such as reductive aldol couplings, asymmetric hydrogenation, asymmetric transfer hydrogenation, asymmetric cyclopropanation, asymmetric direct aldol reaction.