不斉有機変換の新手法

不对称有机转化新方法

• 批准号: 03353009
• 负责人: 中井 武
• 金额: $ 1.28万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (B)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 无数据
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03353009/
• 关键词: 立体化学制御; 不斉合成; 分子認識; 電子移動; 有機金属化学; 炭素ー炭素結合生成

本研究では「不斉有機変換法の開発」に関して次の5つのテ-マをとりあげ、それぞれにおける問題解明と進展に関する調査、企画を行った。(1)有機金属化学に基づく不斉有機変換の新手法,(2)分子認識に基づく不斉有機変換の新手法,(3)電子移動を伴う不斉有機変換の新手法,(4)炭素ー炭素結合生成を伴う不斉有機変換の新手法,(5)不斉有機変換への理論化学的アプロ-チ。まず、上記5つのテ-マに対応して5つのグル-プをつくり、各グル-プ毎に調査研究を行うことにした。また、全体会議を開催して、各分担者が不斉有機変換に関する最近の研究成果と研究遂行上の考え方について報告した。この全体会議では、各分担テ-マごとの調査研究について今後の方針、特に重点領域研究申請への方針について協議した。さらに、数人の世話人を選出して、重点領域研究申請にむけて現在進行中の他の関連する重点領域研究申請グル-プとの調整・協議を数回にわたって行った。以上の結果、本研究グル-プとしては、有機合成化学分野において少なくとも2件の重点領域研究の申請が進行中である本年度は、重点領域研究の申請は見送ることとし、今後、このグル-プを中心にして、新しい総合研究(B)、ひいては重点領域研究を申請すべきとの結論に達し、理・工・薬学部のバランスを考慮して世話人を選出した。要するに、本研究を通して、上記5つのテ-マは、いずれも将来重点領域研究へと発展させるに値するテ-マであることが明らかになるとともに、それにむけての体制づくりに着目することができた。

In this study, there is no opportunity to do so. In this study, we do not have the opportunity to do so. In this study, we do not have the opportunity to do so. (1) Organic metal chemistry does not allow for new techniques, (2) molecular knowledge does not allow for new techniques, (3) computer movement is accompanied by new techniques, (4) carbon is combined to form new techniques for organic chemistry, and (5) there is no mechanism for the development of theoretical chemistry. Please do some research on the following topics: please do some research on this topic. The meeting and plenary meeting will urge the meeting, and all the contributors will have the opportunity to review the latest research results and submit the examination and review report. At the plenary meeting, all participants will participate in the study of the agreement in the future, especially in key areas of research. Applications for research in key fields are now in progress. Applications for research in key fields have been completed several times. The above results, the results of this study, the field study of synthetic chemistry, the application of two key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key fields of research in this year, the application of key field research in this year, the application of key field research in this year, the application of key field research in this year, the application of key field research, the The department of science and engineering has selected a candidate from the department of science and technology. In this study, the key areas of research in the future are the key areas of research in the future.

项目成果

N.Chatani,N.Amishiro,S.Murai: "A New Catalytic Reaction Involving Oxidative Addition of Iodotrimethylsilane to pd (O)" Journal of American Chemical Society. 113. 7778-7780 (1991)

N.Chatani、N.Amishiro、S.Murai：“一种涉及三甲基碘硅烷氧化加成到 pd (O) 的新催化反应”美国化学会杂志。

T.Inokuchi,M.Tsuji,H.Kawafuchi,S.Torii: "Indirect Electroreduction of 2-Alkyl-2-(bromomethyl)-cycloalkanones with Cobaloxime to Form 3-Alkyl-2-alkenones" Journal of Organic Chemistry. 56. 5945-5948 (1991)

T.Inokuchi、M.Tsuji、H.Kawafuchi、S.Torii：“用钴肟间接电还原 2-烷基-2-（溴甲基）-环烷酮形成 3-烷基-2-烯酮”有机化学杂志。