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Activation of Oxygen-containing organic compounds by electron deficient palladium complexes

Activation of Oxygen-containing organic compounds by electron deficient palladium complexes
缺电子钯配合物活化含氧有机化合物
批准号：
08455421
负责人：
INOUE Yoshio
金额：
$4.99万
依托单位：
Tohoku University
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (B)
财政年份：
1996
资助国家：
日本
项目状态：
已结题
起止时间：
1996 至 1998
来源：
https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-08455421/
关键词：
cationic palladium complexcationic rhodium complexcarbon monoxidehydroesterificationhetero Diels-Alder reactionarylstannanesパラジウム錯体カチオン性錯体Diels-Alder反応ロジウム錯体ヘテロDiels‐Alder反応スチレンジエンジエノフィルヒドロエステル化反応

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中文摘要
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英文摘要
1. Exploitation of new reactions catalyzed by cationic palladium complexes.(1) Hetero Diels-Alder reaction of non-activated dienes with aldehydes has been found to be catalyzed by cationic palladium complexes.(2) Regioselective hydroesterification of styrene has been found to be catalyzed by cationic palladium complexes.(3) Novel cyclocarbonylation of 3-butyn-1-ol has been found to be catalyzed by cationic palladium complexes.(4) Selective synthesis of fulgides via carbonylation of 1,4-diols has been found In be catalyzed by cationic palladium complexes.(5) Novel di- and trimerization of strained alkenes and carbon monoxide has been found to be catalyzed by cationic palladium complexes.2. Exploitation of new reactions catalyzed by cationic rhodium complexes.(1) Novel arylation of aldehydes with arylstannanes has been found to be catalyzed by cationic rhodium complexes.(2) Conjugate arylation of alpha, beta-unsaturated ketones with arylstannanes has been found to be catalyzed by cationic rhodium complexes.
期刊论文(28)
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会议论文
S.Oi: "A Cationic Palladium(II) Complex-Catalyzed Diel-Alder Reaction" Tetrahedron Letters. 39. 6253-6256 (1998)
S.Oi：“阳离子钯 (II) 络合物催化的 Diel-Alder 反应”四面体快报。
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通讯作者：
Shuichi Oi: "Rhodium‐catalyzed arylation of aldehydes with arylstannanes" Chemical Communications. 1621-1622 (1997)
Shuichi Oi：“铑催化的醛与芳基锡烷的芳基化”化学通讯 1621-1622 (1997)。
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通讯作者：
S. Oi: "Regioselective hydroesterification of styrene catalyzed by cationic palladium (II) complexes under mild conditions" Journal of Molecular Catalysis. 115.2. 289-295 (1997)
S. Oi：“温和条件下阳离子钯 (II) 配合物催化苯乙烯的区域选择性加氢酯化”《分子催化杂志》。
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通讯作者：
S.Oi: "Regioseletive hydroesterification of styrene catalyzed by cationic palladium (II) complexes under mild conditions" Journal of Molecular Catalysis A : Chemical. 115. 289-295 (1997)
S.Oi：“温和条件下阳离子钯 (II) 配合物催化苯乙烯的区域选择性加氢酯化”《分子催化杂志 A：化学》。
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通讯作者：
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