Development of Molecular Transformation Method Based on Transition-Metal-Catalyzed Reaction Involving Hydrogen-Boron Exchange

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An efficient platinum-catalyzed reaction involving hydrogen-boron exchange on the carbon-carbon double bond has been established, which results in regioand stereoselective construction of organoboron compounds. A rhodium-catalyzed addition reaction of hydrosilane, which is formed in the hydrogen-boron exchange, to the carbon-carbon double bond has also been developed. Finally, sequential molecular transformation involving stereoselective construction of both carbon-carbon double bond and stereogenic carbon centers has been achieved by applying those two reactions.