New evolution of continuous hetero-atomic chemistry

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The oxime ether and the alkoxy amines where the nitrogen atom and the oxygen atom existed continuously were selected as the functional group bearing as consecutive hetero atoms. The continuous multistage reaction of these compounds with low environmental load was developed, and highly efficient and versatile synthetic methods of the heterocyclic compounds contained in a lot of medicines and the biologically active compounds were established. In addition, new polarity inversed reactions of the carbonyl compounds were developed by using these functional groups as an innovative method for carbon-carbon bond formation.