Construction of the spatiotemporal-molecular switching systems based on the dynamic coordination chemistry of chiral and labile metal complexes

本论文的主要工作是基于不稳定金属配合物的动态配位化学，发展时空手性金属配合物体系，取得了以下成果：（1）正方形平面金属配合物中的螺旋度反演编程，（2）基于手性金属配合物的动态结构转换的多开关配合物，（3）树枝状手性金属配合物中的手性整合和动态螺旋度控制，（4）光响应手性金属配合物的构建，（5）刺激响应手性金属折叠体的开发，（6）高配位镧系配合物中手性环境的动态形成。

This research work focused on the development of the spatiotemporal-chiral metal complex systems based on the dynamic coordination chemistry of labile metal complexes and the following results have been obtained; (1) helicity inversion programing in a square planar metal complex, (2) multi-switching complex based on the dynamic structural conversion of chiral metal complex, (3) chirality integration and dynamic helicity control in dendritic chiral metal complex, (4) construction of a photo-responsive chiral metal complex, (5) development of the stimuli-responsive chiral metal foldamers, (6) dynamic formation of chiral environment in highly coordinated lanthanide complexes.