Construction of photoactive supramolecular complexes and the arrangement control of the supramolecular on metallic substrate

合成了与二乙基邻二氮杂菲相连的Ru(II)-Ph(II)超分子络合物，用于研究这些超分子络合物在光激发状态下的光诱导电子转移过程，并制备了取代苯硫酚的Ru(II)络合物，用于在金衬底上构建自组装单分子膜。报道了它们在金表面的电化学性质和光物理性质。

The ruthenium(II)-platinum(II) supramolecular complexes linked with diethynylphenanthroline were synthesized for exploring the photoinduced electron transfer process under the photo-excited state in these supramolecular complexes.The ruthenium(II) complexes with thiophenol subsituent were prepared for the construction of self-assemble monolayer on gold substrate. The electrochemical and the photophysical properties of these complexes on gold were reported.