Construction of photoactive supramolecular complexes and the arrangement control of the supramolecular on metallic substrate

合成了钌(II)-铂(II)-二乙基菲罗啉超分子配合物，探讨了这些超分子配合物在光激发态下的光致电子转移过程。制备了噻吩取代钌配合物，用于在金衬底上构建自组装单分子膜。报道了这些配合物在金上的电化学和光物理性质。

The ruthenium(II)-platinum(II) supramolecular complexes linked with diethynylphenanthroline were synthesized for exploring the photoinduced electron transfer process under the photo-excited state in these supramolecular complexes.The ruthenium(II) complexes with thiophenol subsituent were prepared for the construction of self-assemble monolayer on gold substrate. The electrochemical and the photophysical properties of these complexes on gold were reported.