Purchase of a tandem LA-LIBS femtosecond laser system for the UK

为英国购买串联 LA-LIBS 飞秒激光系统

• 批准号: NE/V016911/1
• 负责人: Craig Storey
• 金额: $ 121.73万
• 依托单位: University of Portsmouth
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2021
• 资助国家: 英国
• 起止时间: 2021 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=NE%2FV016911%2F1
• 关键词: Purchase; tandem; LA; LIBS; femtosecond

Earth and environmental scientists tackle diverse issues ranging from the formation of Earth to the fate of ecosystems being stressed by pollution. This requires us to measure the chemical composition of many different samples, including minerals, plastics, dust, and biological materials; this allows us to link physical and biological process (e.g. growth of minerals, breakdown of plastic in the environment, corrosion, dispersal of dust) with chemical ones (e.g. uptake of metals in minerals, release of toxic elements from plastics, transfer of polluting chemicals to plants and animals). Only then can we fully determine sustainable solutions to complex environmental problems, such as (1) how to locate and sustainably mine metals that are critical for building low-carbon infrastructure, (2) how dangerous microplastics are in rivers and oceans, and (3) how to reduce harmful air pollution. Measurement of such a broad range of materials usually requires a multitude of different instruments and methods. In addition, for many materials (e.g. plastic, dust) it is difficult to measure very small fragments in a controlled way. We propose the use of a new instrument, the first of its kind in the UK, that will allow analysis of a vast range of Earth materials and difficult to measure elements to provide high quality data critical for addressing geo-environmental problems.The new instrument capitalises on recent innovations in laser technology, bringing together ultrafast femtosecond laser ablation (fs-LA) with laser induced breakdown spectroscopy (LIBS) into a single system (fs-LA-LIBS). It is uniquely capable of analysing a wide range of materials, as the very short duration pulse laser (femtosecond (fs) or one quadrillionth of a second!) ejects only a very thin surface layer of material and does not heat the sample below. This allows sensitive materials, such as plastic, liquids, biological samples and dust, to be rapidly analysed for their chemical composition. This is measured simultaneously in two ways: 1) LIBS - the laser energy ejects and excites atoms, which emit optical radiation (light) as they cool. Spectrometers measure the wavelength of this optical radiation and convert it into a chemical analysis of the sample, including for elements such as non-metals that are very difficult to measure in other ways. 2) LA - the tiny volume of ejected sample is swept away by a stream of gas into a mass spectrometer, where it enters a 7000degC plasma, (as hot as the Sun's surface), breaking down any remaining molecules and producing charged ions. These are separated by the mass spectrometer according to their mass and charge, providing highly-sensitive measurement of the concentration of trace elements and ratios of different isotopes in the sample. The combination of these technologies in one instrument capable of rapid analysis will be unique to the UK and Europe, and will provide the data required to tackle many major environmental challenges.

地球和环境科学家解决各种问题，从地球的形成到生态系统的命运受到污染的压力。这就要求我们测量许多不同样品的化学成分，包括矿物、塑料、灰尘和生物材料;这使我们能够将物理和生物过程联系起来（例如矿物的生长、塑料在环境中的分解、腐蚀、灰尘的散布）（例如矿物吸收金属、塑料释放有毒元素、污染化学品转移到植物和动物）。只有这样，我们才能充分确定复杂环境问题的可持续解决方案，例如（1）如何定位和可持续开采对建设低碳基础设施至关重要的金属，（2）微塑料在河流和海洋中的危险程度，以及（3）如何减少有害的空气污染。测量如此广泛的材料通常需要多种不同的仪器和方法。此外，对于许多材料（例如塑料、灰尘），很难以受控的方式测量非常小的碎片。我们建议使用一种新的仪器，这是英国第一台此类仪器，它将允许分析各种地球物质和难以测量的元素，为解决地球环境问题提供高质量的数据。新仪器利用了激光技术的最新创新，将超快飞秒激光烧蚀（fs-LA）与激光诱导击穿光谱（LIBS）结合到一个系统（fs-LA-LIBS）中。它是唯一能够分析广泛的材料，作为非常短的持续时间脉冲激光（飞秒（fs）或千万亿分之一秒！）仅蒸发非常薄的材料表面层，并且不加热下面的样品。这使得塑料、液体、生物样品和灰尘等敏感材料能够快速分析其化学成分。这可以通过两种方式同时测量：1）LIBS -激光能量激发和激发原子，原子在冷却时发出光辐射（光）。光谱仪测量这种光辐射的波长，并将其转换为样品的化学分析，包括以其他方式测量非常困难的非金属等元素。2)LA -喷射出的微小体积的样品被气流扫入质谱仪，在那里它进入7000摄氏度的等离子体（与太阳表面一样热），分解任何剩余的分子并产生带电离子。质谱仪根据它们的质量和电荷将它们分离，从而提供对样品中微量元素浓度和不同同位素比例的高灵敏度测量。将这些技术结合在一个能够快速分析的仪器中，将是英国和欧洲独一无二的，并将提供应对许多重大环境挑战所需的数据。