Solid-state NMR Research Service for UK Universities

为英国大学提供的固态核磁共振研究服务

• 批准号: EP/D077532/1
• 负责人: Paul Hodgkinson
• 金额: $ 53.85万
• 依托单位: Durham University
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2006
• 资助国家: 英国
• 起止时间: 2006 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FD077532%2F1
• 关键词: Solid; state; NMR; Research; Service

Solid-state NMR is an important technique for characterising and studying solid materials whether they are homogeneous or heterogeneous, crystalline or amorphous. It can be applied across a wide-range of chemistry including novel organic, inorganic, organometallic and hybrid compounds, polymers (both natural and synthetic), fuels, pharmaceutical and excipients, composites, ceramics, catalysts, liquid crystals and biologically-based systems. This proposal is for a solid-state nuclear magnetic resonance (NMR) research service. The service will be available to members of the UK academic community and will based around a new state-of-the-art 400 MHz spectrometer. It will build upon the well-established and highly-experienced service currently running at Durham. The service will offer experiment planning and interpretation, in addition to providing high-quality spectra. It will promote the application of solid-state NMR to chemical problems and will act as a centre for practical training in solid-state NMR methodology. The EPSRC service will run in parallel to a commercial service supporting the research and development needs of industry. The case for support describes how the service will be structured, how it will operate and how much instrument time will be available to its users. It is proposed that the Service will operate for a period of five years to permit a major equipment upgrade to be carried out and its impact evaluated.

固体核磁共振是表征和研究固体材料的一种重要技术，无论它们是均相的还是非均相的，结晶的还是非晶态的。它可以应用于广泛的化学领域，包括新型有机、无机、有机金属和杂化化合物、聚合物(天然和合成)、燃料、药物和辅料、复合材料、陶瓷、催化剂、液晶和基于生物的系统。这项提议是针对固态核磁共振(核磁共振)研究服务的。这项服务将提供给英国学术界的成员，并将基于一种新的最先进的400 MHz光谱仪。它将建立在目前在达勒姆运营的成熟和经验丰富的服务的基础上。除了提供高质量的光谱外，该服务还将提供实验规划和解释。它将促进固体核磁共振在化学问题上的应用，并将作为固体核磁共振方法学的实践培训中心。EPSRC服务将与支持行业研究和开发需求的商业服务并行运行。支持案例描述了该服务将如何构建、如何运行以及其用户将有多少仪器时间可用。提议该处运作五年，以便进行主要设备升级，并对其影响进行评估。

项目成果

Speciation of chloroindate(III) ionic liquids

• DOI: 10.1039/c0dt00497a
• 发表时间: 2010-01-01
• 期刊: DALTON TRANSACTIONS
• 影响因子: 4
• 作者: Apperley, David C.;Hardacre, Christopher;Villar-Garcia, Ignacio J.
• 通讯作者: Villar-Garcia, Ignacio J.

A study of the chemistry of isomorphous substitution and characterization of Al-ZSM-5 and Sc-ZSM-5 synthesized in fluoride media

• DOI: 10.1134/s0020168507070175
• 发表时间: 2007
• 期刊: Inorganic Materials
• 影响因子: 0.8
• 作者: Cl. T. Briden;C. D. Williams;D. Apperley