Acquisition of Nuclear Magnetic Resonance Spectrometer

本提案要求支持获得一个核磁共振光谱仪，用于以下应用：鉴定半化学物质；有机化合物合成；合成选择性高分子膜的开发与表征来自藻类和植物的生物活性产品；立体化学的研究;模式化合物的漂白和制浆研究环境毒物的跨肝行为（毒理学）；共聚物的结构与溶质的结合固体聚合物-电解质配合物（固态探针）；多位点病毒相关聚合酶抑制剂的结构研究s -杂环的地球化学成因多糖的构象、结晶度和形态（固态探针）；生物转化半纤维素的结构；具有医学意义的寄生原生动物的甘油和糖脂；熔融多环中annelation的控制木材原位脱木质素（固态探针）；木质素降解真菌降解芳香污染物的研究聚合物-聚合物相互作用（固态探针）；昆虫代谢研究；计算机辅助结构解析；昆虫微量半化学物质的结构解析多糖的降解；氯化木质素腐殖质的结构-致突变性关系淀粉降解动力学（固态探针）；阴离子多糖中的阳离子结合位点（固态探针）纤维素低聚物、硫酸皮聚糖、糖胺聚糖、甘露聚糖和半乳甘露聚糖的结构和水合作用（固态探针）。

This proposal requests support to obtaining, an NMR Spectrometer for the following applications: Identification of semiochemicals; Synthesis of organic compounds; Development and characterization of synthetic, selective, polymeric membranes; Biologically active products from algae and plants; Stereochemical studies; Bleaching and pulping studies on model compounds; Transhepatic behavior of environmental toxicants (toxicology); Structure of copolymers and binding of solutes; Solid polymer-electrolyte complexes (solid state probe); Structure of multisite, viral-associated polymerase inhibitors; Geochemical origins of S-heterocyclics; Conformation, crystallinity, and morphology of polysaccharides (solid state probe); Structure of biologically transformed hemicellulose; Glycero- and glycolipids of parasitic protozoans of medical importance; Control of annelation in fused polycyclics; Delignification of wood in situ (solid state probe); Degradation of aromatic pollutants by ligninolytic fungi; Polymer-polymer interactions (solid state probe); Metabolic studies in insects; Computer assisted structure elucidation; Structure elucidation of microgram amounts of insect semiochemicals; Degradation of polysaccharides; Structure-mutagenicity relationships in chlorinated ligno-humics; Kinetics of starch retrogradation (solid state probe); Cation binding sites in anionic polysaccharides (solid state probe); Structure and hydration effects in cellulosic oligomers, dermantan sulfate, a glycosaminoglycan, mannan, and galactomannan (solid state probe).