High Resolution of NMR of Reverse Micelles in Supercritical Fluids

女性职业发展研究机会奖 项目是在分析和表面化学的一般领域 在分离科学和超临界流体领域， 流体. 在1989年5月1日开始的12个月期间， Olesik教授将进行一系列高分辨率的 核磁共振（NMR）实验中，她将 研究反胶束之间的分子相互作用 和超临界流体中的溶质分子。 她具体 将决定AOT反胶束的各种性质 系统和探索溶质的行为，在两个非极性 液体和超临界流体，压力高于5,000 psi。 这个职业发展奖将使教授Olesik， 扩大她的研究能力，包括使用高 作为分子探针。 这项研究成果 可以广泛影响分析化学的各个领域， 特别是在色谱法和质谱法中。

This Research Opportunities for Women Career Advancement Award project is in the general area of analytical and surface chemistry and in the subfields of separations science and supercritical fluids. During the twelve month period beginning 1 May 1989, Professor Olesik will undertake a series of high resolution nuclear magnetic resonance (NMR) experiments in which she will investigate the molecular interactions between reverse micelles and solute molecules in supercritical fluids. Specifically, she will determine various properties of the AOT reverse micelle system and explore the behavior of solutes in both nonpolar liquids and supercritical fluids at pressures above 5,000 psi. This Career Advancement Award will enable Professor Olesik to expand her research capabilities to include the use of high resolution NMR as a molecular probe. The results of this research could impact broadly in various areas of analytical chemistry, particularly in chromatography and mass spectrometry.