Synthesis of Novel Porphyrins with Exocyclic Rings

这项研究是围绕着准备可能的 地球化学中间体，可用于模拟 在有机物中发现的不寻常的石油卟啉结构的形成 沉积物 包括环烷卟啉的化合物， 脱氧叶红始卟啉，内消旋β-乙醇卟啉， 具有稠合环外环的石油卟啉和新卟啉 二聚体是所提出的合成目标之一。 %%% 有了这个RUI奖，合成有机计划是 支持Timothy D博士的研究。最后一次 伊利诺伊州立大学化学系。 拉什教授将把他的研究重点放在合成 卟啉分子化石 这项工作将给一个更好的 了解有机沉积物的起源， 让本科生参与到一个令人兴奋的研究领域中来。

This research is centered around the preparation of possible geochemical intermediates which can be used to model the formation of unusual petroporphyrin structures found in organic sediments. Compounds including cycloalkanoporphyrins, deoxophylloerythroetioporphyrin, meso,beta-ethanoporphyrins, petroporphyrins with fused exocyclic rings and novel porphyrin dimers are among the proposed synthetic targets. %%% With this RUI award, the Synthetic Organic Program is supporting the research of Dr. Timothy D. Lash of the Department of Chemistry at Illinois State University. Professor Lash will focus his research on the synthesis of porphyrin molecular fossils. The work will give a better understanding of the origins of organic sediments and will involve undergraduates in an exciting area of research.