Inorganic Monolayers Fabricated at an Organic Template: Development, Characterization, and Investigation of Two-Dimensional Magnetism

这项研究致力于通过将无机离子和络合物阵列结合到由Langmuir-Blodgett和自组装技术形成的单层组装中来开发无机单层。有机单分子膜将被用作形成无机层的模板。探索了三类无机膜：层状烷基铵金属卤化物、有机载体上制备的金属卤化物、层状金属磷酸盐和磷酸盐。将对新材料进行结构表征，并从两个维度对其磁性进行研究。所提出的工作具有开发高密度、可逆磁记录介质的最终潜力。

This research is concerned with developing inorganic monolayer by incorporating arrays of inorganic ions and complexes into monolayer assemblies formed by Langmuir-Blodgett and self-assembly techniques. Organized organic monolayers will be used as templates for forming inorganic layers. Three classes of inorganic layers are explored: layered alkylammonium metal halides, metal halides prepared on organic host, and layered metal phosphonates and phosphates. The new materials will be characterized structurally, and an investigation of their magnetic properties in two dimensions will be conducted. The proposed work has an ultimate potential for developing high-density, reversible magnetic recording media.