Activation of Oxygen-containing organic compounds by electron deficient palladium complexes

1.阳离子钯配合物催化新反应的开发。(1)非活化二烯与醛的Hewlett-Diels-Alder反应在阳离子钯配合物的催化下进行。(2)研究了阳离子钯配合物催化苯乙烯区域选择性氢酯化反应。(3)研究了阳离子钯配合物催化3-丁炔-1-醇环羰基化反应。(4)研究了阳离子钯配合物催化1，4-二醇羰基化选择性合成俘精酸酐的反应。(5)研究了阳离子钯配合物催化张力烯烃与一氧化碳的二聚和三聚反应.阳离子铑配合物催化新反应的开发。(1)发现了一种新型的铑配合物催化醛与芳基锡烷的芳基化反应。(2)已发现α，β-不饱和酮与芳基锡烷的共轭芳基化可由阳离子铑络合物催化。

1. Exploitation of new reactions catalyzed by cationic palladium complexes.(1) Hetero Diels-Alder reaction of non-activated dienes with aldehydes has been found to be catalyzed by cationic palladium complexes.(2) Regioselective hydroesterification of styrene has been found to be catalyzed by cationic palladium complexes.(3) Novel cyclocarbonylation of 3-butyn-1-ol has been found to be catalyzed by cationic palladium complexes.(4) Selective synthesis of fulgides via carbonylation of 1,4-diols has been found In be catalyzed by cationic palladium complexes.(5) Novel di- and trimerization of strained alkenes and carbon monoxide has been found to be catalyzed by cationic palladium complexes.2. Exploitation of new reactions catalyzed by cationic rhodium complexes.(1) Novel arylation of aldehydes with arylstannanes has been found to be catalyzed by cationic rhodium complexes.(2) Conjugate arylation of alpha, beta-unsaturated ketones with arylstannanes has been found to be catalyzed by cationic rhodium complexes.