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The Supergen Biological Fuel Cells Consortium 2010-2014 (CORE)

The Supergen Biological Fuel Cells Consortium 2010-2014 (CORE)
Supergen 生物燃料电池联盟 2010-2014 (CORE)
批准号:
EP/H019480/1
负责人:
Fraser Armstrong
金额:
$429.92万
依托单位:
依托单位国家:
英国
项目类别:
Research Grant
财政年份:
2010
资助国家:
英国
项目状态:
已结题
起止时间:
2010 至 --

项目摘要

项目成果

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中文摘要
翻译
超级生物燃料电池联盟正在开发先进的技术,利用生物系统的特殊特性来生产能源。燃料电池通过燃料(如氢或甲醇)与氧气(来自空气)在一对电极上发生反应来发电,而不是通过燃烧产生热量。通常,燃料电池需要昂贵的部件,如特殊的催化剂(铂)和膜。相比之下,生物燃料电池使用整个生物体或分离的酶作为催化剂,可能不需要膜。目前正在开发的燃料电池有两种——微生物燃料电池(MFCs)和酶燃料电池。mfc在改善环境和节约能源方面发挥着重要作用,而基于酶的燃料电池(EFCs)为新型燃料电池提供了独特的机会,包括那些可以制造得非常小的燃料电池,用于诸如植入式电源之类的利基应用。mfc利用与电极接触的细菌将有机物(燃料)转化为电能。它们还可以用于从供水中去除(氧化)污染物,其优点是同时产生的电力抵消了修复的能源成本。EFCs利用了酶的高活性、高效率和选择性,认识到在大多数情况下,特别是当连接到电极上时,它们的性能远远优于人造催化剂。该联盟结合了几个领域的专业知识,并计划在几个方面推进该领域。这些包括:对微生物如何在电极上定植有清晰的认识,如何维持有用的细菌,以及如何阻止不需要的微生物定植;了解并改进电荷在细菌和电极之间传递的方式;利用廉价和丰富的材料优化电极设计,重点关注表面化学孔隙率和电导率等因素;设计小型特殊应用的新型燃料电池;最后但并非最不重要的是,寻找替代铂作为氧还原电催化剂的新方法。
英文摘要
The Supergen Biological Fuel Cells Consortium is developing advanced technologies that exploit the special properties of biological systems for energy production. A fuel cell produces electricity by reacting a fuel (such as hydrogen or methanol) with oxygen (from air) at a pair of electrodes instead of by combustion,which produces only heat. Normally, fuel cells require expensive components such as special catalysts (platinum) and membranes. In contrast, biological fuel cells use whole organisms or isolated enzymes as catalysts, and a membrane may not be necessary. Two kinds of fuel cell are under development - microbial fuel cells (MFCs) and enzyme-based fuel cells. MFCs have an important role to play in improving our environment and conserving energy whereas enzyme-based fuel cells (EFCs) provide unique opportunities for new kinds of fuel cells, including ones that can be made very small for niche applications such as implantable power sources. MFCs use bacteria, held in contact with an electrode, to convert organic matter (the fuel) into electrical power. They can also be used to remove (oxidising) contaminants from water supplies with the advantage that the electrical power that is simultaneously produced offsets the energy costs for remediation. EFCs exploit the high activities, efficiencies and selectivities of enzymes, recognising that in most cases, and particularly when attached to an electrode, their performance is far superior to man-made catalysts. The Consortium combines expertise in several areas and plans to advance the field on several fronts. These include the following: developing a clear understanding of how microbes colonise electrodes, how useful bacteria can be sustained and undesirable microbes deterred from colonising; understanding and improving the way that electrical charge is transferred between bacteria and electrodes; optimising the design of electrodes from cheap and abundant materials, focusing on such factors as surface chemistry porosity and conductivity; designing novel fuel cells for small-scale special applications; last but not least, finding new ways to replace platinum as the electrocatalyst for oxygen reduction.
期刊论文(9)
专著(0)
科研奖励(0)
会议论文
DOI: 10.1109/tmech.2010.2090894
发表时间: 2011-02-01
期刊: IEEE-ASME TRANSACTIONS ON MECHATRONICS
影响因子: 6.4
作者: [Anderson, Iain A., Ieropoulos, Ioannis A., Melhuish, Chris]
通讯作者: Melhuish, Chris
DOI: 10.1016/j.carbon.2011.05.022
发表时间: 2011-10-01
期刊: CARBON
影响因子: 10.9
作者: [Amini, Negar, Aguey-Zinsou, Kondo-Francois, Guo, Zheng-Xiao]
通讯作者: Guo, Zheng-Xiao
DOI: 10.1021/ja4042675
发表时间: 2013-10-09
期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
影响因子: 15
作者: [Bachmeier, Andreas, Wang, Vincent C. C., Woolerton, Thomas W., Bell, Sophie, Fontecilla-Camps, Juan C., Can, Mehmet, Ragsdale, Stephen W., Chaudhary, Yatendra S., Armstrong, Fraser A.]
通讯作者: Armstrong, Fraser A.
Fuel Cell Science - Theory, Fundamentals, and Biocatalysis
燃料电池科学 - 理论、基础知识和生物催化
DOI: 10.1002/9780470630693.ch7
发表时间: 2010
期刊:
影响因子: --
作者: [Armstrong F]
通讯作者: Armstrong F
The Electrochemical Leaf:Rapid, Reversible Cycling of Nicotinamide Cofactors for Enzyme-based Organic Synthesis
  • 批准号:
    BB/P023797/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $25.22万
  • 财政年份:
    2017
  • 负责人:
    Fraser Armstrong
  • 依托单位:
How hydrogenases work at the atomic level
  • 批准号:
    BB/N006321/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $92.12万
  • 财政年份:
    2016
  • 负责人:
    Fraser Armstrong
  • 依托单位:
Metal-hydrido intermediates in enzymes: atomic level mechanistic insight and technological applications of hydrogenases
  • 批准号:
    BB/L009722/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $54.4万
  • 财政年份:
    2014
  • 负责人:
    Fraser Armstrong
  • 依托单位:
14-ERASynBio Engineering the chloroplast of microalgae as a chassis for the direct production of solar fuels and chemicals
  • 批准号:
    BB/M005720/1
  • 项目类别:
    Research Grant
  • 资助金额:
    $42.51万
  • 财政年份:
    2014
  • 负责人:
    Fraser Armstrong
  • 依托单位:
海外基金