Harnessing the power of polymer phase interactions in the design of supramolecular interpenetrating networks

在超分子互穿网络设计中利用聚合物相相互作用的力量

• 批准号: 1833479
• 负责人: LaShanda Korley
• 金额: $ 21.72万
• 依托单位: University of Delaware
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-01-01 至 2020-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1833479&HistoricalAwards=false
• 关键词: Harnessing; power; polymer; phase; interactions

NON-TECHNICAL SUMMARY:Biological materials often feature complex assemblies that utilize the interaction between phases possessing disparate mechanical properties to achieve synergistic and highly tunable effects. Incorporation of this nature-inspired structural interplay into synthetic polymeric systems is proposed toward the development of mechanically-robust and functional materials. Their structures and properties will be studied and correlated in this project using a combination of advanced instrumentation. The ability to control and tune the molecular and materials architecture in complex systems addresses key scientific challenges related to mechanically adaptive behavior and controlled transport in new materials development. Such systems have potential use in a range of applications, including biomedical delivery vehicles, sensors, actuators, and membranes, and may potentially also offer advantages in terms of processability. Graduate and undergraduate students will gain exposure to cross-cutting research -- from synthesis to processing -- and utilize these advances in the areas of mentorship and community outreach. A mentoring platform for female students and post-docs, particularly from underrepresented groups, to engage in dialogue regarding shared experiences and career pathways will be supported. An expanded partnership with a K-12 all-female independent school will provide hands-on demonstrations, career development, and safety/ethics training during a two-week science/engineering exposure program for high-school girls. TECHNICAL SUMMARY:Supramolecular associations have been widely explored in elastomers, blends, and copolymer systems, and have motivated interest in the utilization of dynamic associations in the design of interpenetrating polymer networks (IPNs). IPNs provide a robust platform to explore the role of supramolecular motifs as a toughening mechanism due to the intimate interaction of the polymer phases. This research program will elucidate structural parameters and guiding principles to direct fabrication of supramolecular IPNs with tunable interfacial interactions, tailored structural heterogeneity, and synergistic mechanical behavior. Three classes of supramolecular IPNs will be explored that utilize: (1) complementary and orthogonal supramolecular associations with focus on how motifs of varying interaction strength/organization influence microstructure development and dynamics, (2) self-complementary and complementary hydrogen bonding associations with an emphasis on the correlation between the resulting IPN morphology, mechanics, and supramolecular response, and (3) particulate-reinforcement as an approach to control phase coarsening, mechanical behavior, and functionality. A full suite of structural, thermal, mechanical, and morphological characterization techniques will be utilized, including variable temperature nuclear magnetic resonance, fluorescence spectroscopy, tensile testing, dynamic mechanical analysis, atomic force microscopy, rheology, scanning electron microscopy, and X-ray and neutron scattering.

非技术摘要：生物材料通常具有复杂的组件，这些组件利用具有不同机械性能的相之间的相互作用来实现协同和高度可调的效果。建议将这种受自然启发的结构相互作用纳入合成聚合物系统，以开发机械坚固的功能材料。 在这个项目中，将使用先进仪器的组合来研究它们的结构和性质并进行关联。 控制和调整复杂系统中的分子和材料结构的能力解决了与新材料开发中的机械自适应行为和受控传输相关的关键科学挑战。此类系统在一系列应用中具有潜在用途，包括生物医学输送工具、传感器、执行器和膜，并且还可能在可加工性方面提供优势。 研究生和本科生将接触到从合成到加工的跨领域研究，并在指导和社区外展领域利用这些进步。将支持为女学生和博士后（特别是来自代表性不足群体的女学生和博士后）建立一个指导平台，以参与有关共享经验和职业道路的对话。与一所 K-12 全女性独立学校扩大合作伙伴关系，将在为期两周的科学/工程接触项目中为高中女生提供实践演示、职业发展和安全/道德培训。技术摘要：超分子缔合已在弹性体、共混物和共聚物体系中得到广泛探索，并激发了人们对在互穿聚合物网络 (IPN) 设计中利用动态缔合的兴趣。由于聚合物相的密切相互作用，互穿网络提供了一个强大的平台来探索超分子基序作为增韧机制的作用。该研究计划将阐明直接制造具有可调界面相互作用、定制结构异质性和协同机械行为的超分子互穿网络的结构参数和指导原则。将探索三类超分子 IPN，利用：（1）互补和正交超分子关联，重点关注不同相互作用强度/组织的基序如何影响微观结构发展和动力学，（2）自互补和互补氢键关联，重点关注所得 IPN 形态、力学和超分子之间的相关性 响应，(3) 颗粒增强作为控制相粗化、机械行为和功能的方法。将利用全套结构、热、机械和形态表征技术，包括变温核磁共振、荧光光谱、拉伸测试、动态力学分析、原子力显微镜、流变学、扫描电子显微镜以及X射线和中子散射。