The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles
The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles
批准号:
396285167
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
起止时间:
中文摘要
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英文摘要
Borylenes are low-oxidation-state boron compounds that are either highly electron-rich or simultaneously electron-rich and -poor ("superambiphiles"). These properties impart borylenes with fascinating reactivity, however, this chemistry remains underdeveloped, hampering their undeniable synthetic potential. This renewal proposal builds on exciting results from the first funding period and targets both electron-rich tricoordinate borylenes and superambiphilic dicoordinate borylenes, developing new methods for their synthesis and novel examples, uncovering unique reactivity of borylenes that is inaccessible with other reagents, and identifying stand-out performers from among them in terms of synthetic ease and ability to activate challenging substrates.
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批准号:396769488
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2018
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
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批准号:325229020
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2017
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Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
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批准号:271723449
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2015
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依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
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批准号:242159665
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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依托单位:
Metal-Mediated Cyclisation of Iminoboranes: Organometallic Chemistry and Functional BN-Isosteres
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批准号:238305216
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Reduction of Mono- and Diboranes(4)
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批准号:221758282
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2012
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Dynamic Metal-to-Element Dative Bonds and their Applications Beyond the Molecule
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批准号:192178519
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Chemistry of Free Boroles
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批准号:186904585
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Boryl- und Borylenkomplexe von Palladium und Platin
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批准号:24798567
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2006
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron density distribution in borylene complexes
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批准号:5449393
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项目类别:Priority Programmes
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资助金额:$0.0万
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财政年份:2005
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktivität von Bor-verbrückten Metallocenophanen und verwandten Verbindungen
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批准号:5451600
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2005
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依托单位:
Synthese, Struktur und Reaktivität von Borylenkomplexen
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批准号:5428093
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2004
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktionen von Übergangsmetallboryl- und -borylenkomplexen
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批准号:5308072
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:1996
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry
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批准号:446663029
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资助金额:$0.0万
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财政年份:--
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依托单位:
Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages
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批准号:450280494
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资助金额:$0.0万
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财政年份:--
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依托单位:
Boraheterocumulenes: Versatile Building Blocks for the Construction of B–E Multiple Bond Species and B,E-Doped Heterocycles
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批准号:530906430
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
This proposal aims to prepare the first polymers based on chains of boron atoms, and to utilise their unique properties
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批准号:390765178
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项目类别:Reinhart Koselleck Projects
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资助金额:$0.0万
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财政年份:--
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依托单位:
Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Neutral diborabenzenes – highly electron-rich systems for classical arene-type reactivity, bond activation, and catalysis
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批准号:452730967
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
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批准号:469029582
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
海外基金