The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles

硼烯及其产物的化学：反应性超级供体和超级双亲化合物

• 批准号: 396285167
• 负责人: Professor Dr. Holger Braunschweig
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/396285167?language=en
• 关键词: Chemistry; Borylenes; their; Products; Reactive

Borylenes are low-oxidation-state boron compounds that are either highly electron-rich or simultaneously electron-rich and -poor ("superambiphiles"). These properties impart borylenes with fascinating reactivity, however, this chemistry remains underdeveloped, hampering their undeniable synthetic potential. This renewal proposal builds on exciting results from the first funding period and targets both electron-rich tricoordinate borylenes and superambiphilic dicoordinate borylenes, developing new methods for their synthesis and novel examples, uncovering unique reactivity of borylenes that is inaccessible with other reagents, and identifying stand-out performers from among them in terms of synthetic ease and ability to activate challenging substrates.

borylenes是低氧化态硼化合物，它们是高度富含电子的或同时富含电子和-Door（“ Superabiphiles”）的。这些特性以引人入胜的反应性赋予了borylenes，但是，这种化学仍然不发达，从而阻碍了其不可否认的合成潜力。 This renewal proposal builds on exciting results from the first funding period and targets both electron-rich tricoordinate borylenes and superambiphilic dicoordinate borylenes, developing new methods for their synthesis and novel examples, uncovering unique reactivity of borylenes that is inaccessible with other reagents, and identifying stand-out performers from among them in terms of synthetic ease and ability to activate challenging基材。