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The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles

The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles
硼烯及其产物的化学:反应性超级供体和超级双亲化合物
批准号:
396285167
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
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英文摘要
Borylenes are low-oxidation-state boron compounds that are either highly electron-rich or simultaneously electron-rich and -poor ("superambiphiles"). These properties impart borylenes with fascinating reactivity, however, this chemistry remains underdeveloped, hampering their undeniable synthetic potential. This renewal proposal builds on exciting results from the first funding period and targets both electron-rich tricoordinate borylenes and superambiphilic dicoordinate borylenes, developing new methods for their synthesis and novel examples, uncovering unique reactivity of borylenes that is inaccessible with other reagents, and identifying stand-out performers from among them in terms of synthetic ease and ability to activate challenging substrates.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
  • 批准号:
    396769488
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2018
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    $0.0万
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  • 负责人:
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    271723449
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
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    2015
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Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
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    242159665
  • 项目类别:
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    $0.0万
  • 财政年份:
    2013
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
海外基金