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Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis

Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis
利用不含过渡金属的氮活化进行有机和无机合成
批准号:
494871290
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
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英文摘要
The conversion of atmospheric nitrogen to useful products using molecular species has been a major goal of inorganic chemistry for decades. Our recent development of N2 activation and functionalization at a main-group species, a dicoordinate borylene, has opened the possibility of a transition-metal free alternative for nitrogen conversion. Our initial N2 activation reactions, which produce bisborylene-N2 and -N4 adducts have provided a number of novel nitrogen-containing species that suggest a potentially vast landscape of further chemical conversions. This project envisages a focused exploration of the synthetic possibilities opened by our borylene-mediated N2 activation, towards targets of application-based and fundamental interest.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
  • 批准号:
    396769488
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2018
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
  • 批准号:
    325229020
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2017
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
  • 批准号:
    271723449
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2015
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
  • 批准号:
    242159665
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2013
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
国内基金
海外基金
Baryogenesis, Dark Matter and Nanohertz Gravitational Waves from a Dark Supercooled Phase Transition
  • 批准号:
    24ZR1429700
  • 项目类别:
    省市级项目
  • 资助金额:
    --
  • 批准年份:
    2024
  • 负责人:
    YUICHIRO NAKAI
  • 依托单位:
以果蝇为模式研究纤毛过渡纤维(Transition fibers)的形成和功能