Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis
Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis
批准号:
494871290
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
起止时间:
中文摘要
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英文摘要
The conversion of atmospheric nitrogen to useful products using molecular species has been a major goal of inorganic chemistry for decades. Our recent development of N2 activation and functionalization at a main-group species, a dicoordinate borylene, has opened the possibility of a transition-metal free alternative for nitrogen conversion. Our initial N2 activation reactions, which produce bisborylene-N2 and -N4 adducts have provided a number of novel nitrogen-containing species that suggest a potentially vast landscape of further chemical conversions. This project envisages a focused exploration of the synthetic possibilities opened by our borylene-mediated N2 activation, towards targets of application-based and fundamental interest.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
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批准号:396769488
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2018
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
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批准号:325229020
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2017
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
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批准号:271723449
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2015
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
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批准号:242159665
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Metal-Mediated Cyclisation of Iminoboranes: Organometallic Chemistry and Functional BN-Isosteres
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批准号:238305216
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Reduction of Mono- and Diboranes(4)
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批准号:221758282
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2012
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Dynamic Metal-to-Element Dative Bonds and their Applications Beyond the Molecule
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批准号:192178519
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Chemistry of Free Boroles
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批准号:186904585
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Boryl- und Borylenkomplexe von Palladium und Platin
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批准号:24798567
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2006
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron density distribution in borylene complexes
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批准号:5449393
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项目类别:Priority Programmes
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资助金额:$0.0万
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财政年份:2005
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktivität von Bor-verbrückten Metallocenophanen und verwandten Verbindungen
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批准号:5451600
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2005
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktivität von Borylenkomplexen
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批准号:5428093
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2004
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktionen von Übergangsmetallboryl- und -borylenkomplexen
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批准号:5308072
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:1996
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry
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批准号:446663029
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages
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批准号:450280494
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles
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批准号:396285167
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Boraheterocumulenes: Versatile Building Blocks for the Construction of B–E Multiple Bond Species and B,E-Doped Heterocycles
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批准号:530906430
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
This proposal aims to prepare the first polymers based on chains of boron atoms, and to utilise their unique properties
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批准号:390765178
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项目类别:Reinhart Koselleck Projects
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Neutral diborabenzenes – highly electron-rich systems for classical arene-type reactivity, bond activation, and catalysis
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批准号:452730967
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Diborenium and Diborynium Cations: Combining Hypovalency, Multiple Bonding, Positive Charge and Unpaired Electrons
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批准号:469029582
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
国内基金
海外基金
Baryogenesis, Dark Matter and Nanohertz Gravitational Waves from a Dark
Supercooled Phase Transition
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批准号:24ZR1429700
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项目类别:省市级项目
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资助金额:--
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批准年份:2024
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负责人:YUICHIRO NAKAI
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依托单位:
以果蝇为模式研究纤毛过渡纤维(Transition fibers)的形成和功能
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批准号:31871357
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项目类别:面上项目
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资助金额:60.0万元
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批准年份:2018
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负责人:卫青
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依托单位: