Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis

利用不含过渡金属的氮活化进行有机和无机合成

• 批准号: 494871290
• 负责人: Professor Dr. Holger Braunschweig
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/494871290?language=en
• 关键词: Exploiting; Transition; Metal; Free; Nitrogen

The conversion of atmospheric nitrogen to useful products using molecular species has been a major goal of inorganic chemistry for decades. Our recent development of N2 activation and functionalization at a main-group species, a dicoordinate borylene, has opened the possibility of a transition-metal free alternative for nitrogen conversion. Our initial N2 activation reactions, which produce bisborylene-N2 and -N4 adducts have provided a number of novel nitrogen-containing species that suggest a potentially vast landscape of further chemical conversions. This project envisages a focused exploration of the synthetic possibilities opened by our borylene-mediated N2 activation, towards targets of application-based and fundamental interest.

几十年来，利用分子物种将大气氮转化为有用的产品一直是无机化学的主要目标。我们最近开发的N2活化和功能化的主组物种，二配位亚硼基，开辟了一个过渡金属的替代氮转化的可能性。我们最初的N2活化反应，产生bisborylene-N2和-N4加合物，提供了一些新的含氮物种，这表明进一步的化学转化的潜在广阔的前景。该项目设想集中探索由我们的硼介导的N2活化打开的合成可能性，以实现基于应用和根本利益的目标。