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Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages

Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages
亚价铝:用于生成同双原子和异双原子 Al-E 连接的多功能试剂
批准号:
450280494
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
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英文摘要
The realization of main-group molecules with oxidations states lower than those commonly observed has become an essential element of modern chemistry. Their high potential in further applications, however, inspired an increasing number of chemists worldwide to overcome the inherent synthetic challenges involved. Despite recent advances, subvalent aluminum compounds are still underrepresented, notwithstanding their unique reactivity patterns. This proposal is based on our new access to monomeric CpAl(I) derivatives, and on our expertise in borylene chemistry, and involves (i) the full exploration of CpAl(I) chemistry, and (ii) the establishment of an unprecedented type of Al(I) molecules, i.e. doubly base-stabilized alumylenes.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
  • 批准号:
    396769488
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2018
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
  • 批准号:
    325229020
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2017
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
  • 批准号:
    271723449
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2015
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
  • 批准号:
    242159665
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2013
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
国内基金
海外基金
Aluminum/CFRP 混合管界面分层对渐进折叠机制影响研究
  • 批准号:
    ZCLQN26E0501
  • 项目类别:
    省市级项目
  • 资助金额:
    --
  • 批准年份:
    2026
  • 负责人:
    沈勇
  • 依托单位: